TY - JOUR
T1 - Development of highly microporous activated carbon from the alcoholic beverage industry organic by-products
AU - Nieto-Delgado, C.
AU - Terrones, M.
AU - Rangel-Mendez, J. R.
N1 - Funding Information:
This work was supported by the following grants: FMSLP-2008-C02-99664 (JRRM), PhD scholarship 204158 (CND), 56787 (Laboratory for Nanoscience and Nanotechnology Research-LINAN) 45772 (MT), 41464-Inter American Collaboration (MT), 2004-01-013/SALUD-CONACYT (MT), and Fondo Mixto de San Luis Potosí 63001 S-3908 (MT). The authors gratefully acknowledge Dulce Partida Gutiérrez, Guillermo Vidriales Escobar and Daniel Ramírez González for their technical support. Finally we thank FOMIX-SLP ( FMSLP-2008-C02-106795 ) for the financial support to disseminate these results.
Copyright:
Copyright 2011 Elsevier B.V., All rights reserved.
PY - 2011/1
Y1 - 2011/1
N2 - This work has the aim to employ the agave bagasse, a waste from Tequila and Mescal industries, to obtain a product of high commercial value such as activated carbon. The activated carbon production methodology was based on a chemical activation, by using ZnCl2 and H3PO4 as activating agent and agave bagasse as a natural source of carbon. The activation temperature (150-450 °C), activation time (0-60 min) and weight ratio of activating agent to precursor (0.2-4) were studied. The produced carbon materials were characterized by scanning electron microscopy (SEM), thermogravimetric analysis (TGA) and nitrogen physisorption at -196 °C. In addition, the activating agent recovery was evaluated. We were able to obtain highly microporous activated carbons with micropore volumes between 0.24 and 1.20 cm3/g and a surface area within 300 and 2139 m2/g. These results demonstrated the feasibility to treat the industrial wastes of the Tequila and Mescal industries, being this wastes an excellent precursor to produce highly microporous activated carbons that can be processed at low activation temperatures in short times, with the possibility of recycling the activating agent.
AB - This work has the aim to employ the agave bagasse, a waste from Tequila and Mescal industries, to obtain a product of high commercial value such as activated carbon. The activated carbon production methodology was based on a chemical activation, by using ZnCl2 and H3PO4 as activating agent and agave bagasse as a natural source of carbon. The activation temperature (150-450 °C), activation time (0-60 min) and weight ratio of activating agent to precursor (0.2-4) were studied. The produced carbon materials were characterized by scanning electron microscopy (SEM), thermogravimetric analysis (TGA) and nitrogen physisorption at -196 °C. In addition, the activating agent recovery was evaluated. We were able to obtain highly microporous activated carbons with micropore volumes between 0.24 and 1.20 cm3/g and a surface area within 300 and 2139 m2/g. These results demonstrated the feasibility to treat the industrial wastes of the Tequila and Mescal industries, being this wastes an excellent precursor to produce highly microporous activated carbons that can be processed at low activation temperatures in short times, with the possibility of recycling the activating agent.
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U2 - 10.1016/j.biombioe.2010.08.025
DO - 10.1016/j.biombioe.2010.08.025
M3 - Article
AN - SCOPUS:78650536631
SN - 0961-9534
VL - 35
SP - 103
EP - 112
JO - Biomass and Bioenergy
JF - Biomass and Bioenergy
IS - 1
ER -
