Diffusion of a multi-component plasma

Diffusion in a weakly ionized plasma composed of negative ions as well as positive ions is examined using appropriate linearized fluid equations. For initial, electrically neutral, density perturbations of the form exp(ikx) the diffusion process is characterized by electrical non-neutrality and by three stages or time scales. For equal positive and negative ion diffusion coefficients these stages are in general (1) equilibration of the electron gas so that pressure gradient and electric forces are balanced (2) ambipolar-like diffusion of all three species, and concluding with (3) free ion diffusion. The details of the process are governed by the product kλ_e (wave number times electron Debye length) and the ambient ratio of negative ion to electron number density. Numerical and analytic results for separate positive and negative diffusion coefficients show added complexity which is briefly described. These results or the more complete numerical solutions find application to the lower D region of the ionosphere.