Effect of aromaticity on the rate of azaquinone methide-mediated release of benzylic phenols

Kyle M. Schmid; Scott T. Phillips

doi:10.1002/poc.3129

Effect of aromaticity on the rate of azaquinone methide-mediated release of benzylic phenols

Kyle M. Schmid, Scott T. Phillips

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

Herein we use small molecule models of stimuli-induced degradable/ depolymerizable polymers to demonstrate that less aromatic releasing units provide faster rates of azaquinone methide-mediated release of benzylic phenols (a surrogate for a group released in a polymer) than highly aromatic releasing units.

Original language	English (US)
Pages (from-to)	608-610
Number of pages	3
Journal	Journal of Physical Organic Chemistry
Volume	26
Issue number	7
DOIs	https://doi.org/10.1002/poc.3129
State	Published - Jul 2013

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Organic Chemistry

Access to Document

10.1002/poc.3129

Cite this

@article{a3382fc077314262a3cdb760c8288c76,

title = "Effect of aromaticity on the rate of azaquinone methide-mediated release of benzylic phenols",

abstract = "Herein we use small molecule models of stimuli-induced degradable/ depolymerizable polymers to demonstrate that less aromatic releasing units provide faster rates of azaquinone methide-mediated release of benzylic phenols (a surrogate for a group released in a polymer) than highly aromatic releasing units.",

author = "Schmid, {Kyle M.} and Phillips, {Scott T.}",

year = "2013",

month = jul,

doi = "10.1002/poc.3129",

language = "English (US)",

volume = "26",

pages = "608--610",

journal = "Journal of Physical Organic Chemistry",

issn = "0894-3230",

publisher = "John Wiley and Sons Ltd",

number = "7",

}

TY - JOUR

T1 - Effect of aromaticity on the rate of azaquinone methide-mediated release of benzylic phenols

AU - Schmid, Kyle M.

AU - Phillips, Scott T.

PY - 2013/7

Y1 - 2013/7

N2 - Herein we use small molecule models of stimuli-induced degradable/ depolymerizable polymers to demonstrate that less aromatic releasing units provide faster rates of azaquinone methide-mediated release of benzylic phenols (a surrogate for a group released in a polymer) than highly aromatic releasing units.

AB - Herein we use small molecule models of stimuli-induced degradable/ depolymerizable polymers to demonstrate that less aromatic releasing units provide faster rates of azaquinone methide-mediated release of benzylic phenols (a surrogate for a group released in a polymer) than highly aromatic releasing units.

UR - http://www.scopus.com/inward/record.url?scp=84879231530&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84879231530&partnerID=8YFLogxK

U2 - 10.1002/poc.3129

DO - 10.1002/poc.3129

M3 - Article

AN - SCOPUS:84879231530

SN - 0894-3230

VL - 26

SP - 608

EP - 610

JO - Journal of Physical Organic Chemistry

JF - Journal of Physical Organic Chemistry

IS - 7

ER -

Effect of aromaticity on the rate of azaquinone methide-mediated release of benzylic phenols

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this