Effect of the polymer glass transition on the chromatographic retention volumes

J. S. Vrentas; C. M. Vrentas

doi:10.1002/app.21680

Effect of the polymer glass transition on the chromatographic retention volumes

J. S. Vrentas, C. M. Vrentas

Chemical Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

Theoretical developments are presented that explain four experimental observations concerning the temperature dependence of Chromatographic specific retention volumes. A theoretical framework is proposed for a method that can be used to determine the glass-transition temperature of the pure polymer and for a method of characterizing the concentration dependence of the glass-transition temperature of a polymer-solvent system.

Original language	English (US)
Pages (from-to)	793-796
Number of pages	4
Journal	Journal of Applied Polymer Science
Volume	97
Issue number	3
DOIs	https://doi.org/10.1002/app.21680
State	Published - Aug 5 2005

All Science Journal Classification (ASJC) codes

Chemistry(all)
Surfaces, Coatings and Films
Polymers and Plastics
Materials Chemistry

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10.1002/app.21680

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abstract = "Theoretical developments are presented that explain four experimental observations concerning the temperature dependence of Chromatographic specific retention volumes. A theoretical framework is proposed for a method that can be used to determine the glass-transition temperature of the pure polymer and for a method of characterizing the concentration dependence of the glass-transition temperature of a polymer-solvent system.",

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AB - Theoretical developments are presented that explain four experimental observations concerning the temperature dependence of Chromatographic specific retention volumes. A theoretical framework is proposed for a method that can be used to determine the glass-transition temperature of the pure polymer and for a method of characterizing the concentration dependence of the glass-transition temperature of a polymer-solvent system.

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Effect of the polymer glass transition on the chromatographic retention volumes

Abstract

All Science Journal Classification (ASJC) codes

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