TY - JOUR
T1 - Electrocaloric Performance of Multilayer Ceramic Chips
T2 - Effect of Geometric Structure Induced Internal Stress
AU - Cheng, Li Qian
AU - Yan, Yongke
AU - Li, Xiaotian
AU - Xiong, Xiangming
AU - Chen, Xin
AU - Zhu, Li Feng
AU - Li, Wenjie
AU - Chen, Kai
AU - Sanghadasa, Mohan
AU - Priya, Shashank
N1 - Publisher Copyright:
© 2021 American Chemical Society.
PY - 2021/8/18
Y1 - 2021/8/18
N2 - Driven by an ever-growing demand for environmentally benign cooling systems, the past decade has witnessed the booming development in the field of electrocaloric (EC) cooling technology, which is considered as a promising solid-state cooling approach. Multilayer ceramic chip capacitors (MLCCs) represent the optimum structure for EC cooling elements because of large breakdown strengths, low driving voltages, and high macroscopic volumes of active EC materials. However, fundamental relationships between the geometric parameters of MLCCs and the EC coefficient are less understood. In this study, 0.92Pb(Mg1/3Nb2/3)O3-0.08PbTiO3 (PMN-PT) MLCCs with controlled configurations, such as active/inactive layer thickness, number of layers, and active volume ratio, were fabricated, and their EC performance was evaluated. The electric properties of the MLCCs are confirmed to be closely related to the geometric structure, which influences not only the heat flow but also the internal stress, resulting in the variability of EC performance and reliability/breakdown strength. The internal stress arises due to the residual thermal stress originating from the densification-related shrinkage, thermal expansion mismatch during the sintering, and clamping stress arising from the inactive area due to the large strain from the active area under a high electric field. The geometric structure-based stress distribution and the magnitude of stress on the active layers in MLCCs were determined by finite element modeling (FEM) and correlated with the experimental EC coefficients. The results reveal that a low inactive volume percentage is beneficial toward increasing the breakdown field and enhancement of EC performance because of reduced clamping stress on active EC material.
AB - Driven by an ever-growing demand for environmentally benign cooling systems, the past decade has witnessed the booming development in the field of electrocaloric (EC) cooling technology, which is considered as a promising solid-state cooling approach. Multilayer ceramic chip capacitors (MLCCs) represent the optimum structure for EC cooling elements because of large breakdown strengths, low driving voltages, and high macroscopic volumes of active EC materials. However, fundamental relationships between the geometric parameters of MLCCs and the EC coefficient are less understood. In this study, 0.92Pb(Mg1/3Nb2/3)O3-0.08PbTiO3 (PMN-PT) MLCCs with controlled configurations, such as active/inactive layer thickness, number of layers, and active volume ratio, were fabricated, and their EC performance was evaluated. The electric properties of the MLCCs are confirmed to be closely related to the geometric structure, which influences not only the heat flow but also the internal stress, resulting in the variability of EC performance and reliability/breakdown strength. The internal stress arises due to the residual thermal stress originating from the densification-related shrinkage, thermal expansion mismatch during the sintering, and clamping stress arising from the inactive area due to the large strain from the active area under a high electric field. The geometric structure-based stress distribution and the magnitude of stress on the active layers in MLCCs were determined by finite element modeling (FEM) and correlated with the experimental EC coefficients. The results reveal that a low inactive volume percentage is beneficial toward increasing the breakdown field and enhancement of EC performance because of reduced clamping stress on active EC material.
UR - http://www.scopus.com/inward/record.url?scp=85113751753&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85113751753&partnerID=8YFLogxK
U2 - 10.1021/acsami.1c09911
DO - 10.1021/acsami.1c09911
M3 - Article
C2 - 34351756
AN - SCOPUS:85113751753
SN - 1944-8244
VL - 13
SP - 38508
EP - 38516
JO - ACS Applied Materials and Interfaces
JF - ACS Applied Materials and Interfaces
IS - 32
ER -