Electrochemical Cell Design for Emf Measurements of Liquid Nd-Bi Alloys via Coulombic Titration in LiCl–KCl–NdCl3 Electrolyte

Sanghyeok Im; Nathan D. Smith; Stephanie Castro Baldivieso; Hojong Kim

doi:10.1007/978-3-030-92662-5_30

Electrochemical Cell Design for Emf Measurements of Liquid Nd-Bi Alloys via Coulombic Titration in LiCl–KCl–NdCl₃ Electrolyte

Sanghyeok Im, Nathan D. Smith, Stephanie Castro Baldivieso, Hojong Kim

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

2 Scopus citations

Abstract

Using an electrochemical cell containing a two-phase Nd-Sn alloy (x_Nd = 0.10) in LiCl–KCl–NdCl₃ (1 mol%) as a reference electrode, coulometric titration emf measurements at various cathodic current densities (10–100 mA cm⁻²) were performed to evaluate the stability of the Nd-Sn electrode and corroborate emf values for Nd (in Bi) at T = 873 K. The potential difference between two identical Nd-Sn reference electrodes was measured before/after the electrochemical evaluation for 45 days, and the stability of the cell for the long-term operation was verified. The emf values of Nd (in liquid Bi) titrated at various current densities were consistent at each Nd concentration, demonstrating the reliability of the cell.

Original language	English (US)
Title of host publication	Rare Metal Technology, 2022
Editors	Takanari Ouchi, Gisele Azimi, Kerstin Forsberg, Hojong Kim, Shafiq Alam, Neale R. Neelameggham, Alafara Abdullahi Baba, Hong Peng
Publisher	Springer Science and Business Media Deutschland GmbH
Pages	317-324
Number of pages	8
ISBN (Print)	9783030926618
DOIs	https://doi.org/10.1007/978-3-030-92662-5_30
State	Published - 2022
Event	8th Symposium on Rare Metal Extraction and Processing held at the TMS Annual Meeting and Exhibition, 2022 - Anaheim, United States Duration: Feb 27 2022 → Mar 3 2022

Publication series

Name	Minerals, Metals and Materials Series
Volume	Part F
ISSN (Print)	2367-1181
ISSN (Electronic)	2367-1696

Conference

Conference	8th Symposium on Rare Metal Extraction and Processing held at the TMS Annual Meeting and Exhibition, 2022
Country/Territory	United States
City	Anaheim
Period	2/27/22 → 3/3/22

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Energy Engineering and Power Technology
Mechanics of Materials
Metals and Alloys
Materials Chemistry

Access to Document

10.1007/978-3-030-92662-5_30

Cite this

Im, S., Smith, N. D., Baldivieso, S. C., & Kim, H. (2022). Electrochemical Cell Design for Emf Measurements of Liquid Nd-Bi Alloys via Coulombic Titration in LiCl–KCl–NdCl₃ Electrolyte. In T. Ouchi, G. Azimi, K. Forsberg, H. Kim, S. Alam, N. R. Neelameggham, A. A. Baba, & H. Peng (Eds.), Rare Metal Technology, 2022 (pp. 317-324). (Minerals, Metals and Materials Series; Vol. Part F). Springer Science and Business Media Deutschland GmbH. https://doi.org/10.1007/978-3-030-92662-5_30

Im, Sanghyeok ; Smith, Nathan D. ; Baldivieso, Stephanie Castro et al. / Electrochemical Cell Design for Emf Measurements of Liquid Nd-Bi Alloys via Coulombic Titration in LiCl–KCl–NdCl₃ Electrolyte. Rare Metal Technology, 2022. editor / Takanari Ouchi ; Gisele Azimi ; Kerstin Forsberg ; Hojong Kim ; Shafiq Alam ; Neale R. Neelameggham ; Alafara Abdullahi Baba ; Hong Peng. Springer Science and Business Media Deutschland GmbH, 2022. pp. 317-324 (Minerals, Metals and Materials Series).

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title = "Electrochemical Cell Design for Emf Measurements of Liquid Nd-Bi Alloys via Coulombic Titration in LiCl–KCl–NdCl3 Electrolyte",

abstract = "Using an electrochemical cell containing a two-phase Nd-Sn alloy (xNd = 0.10) in LiCl–KCl–NdCl3 (1 mol%) as a reference electrode, coulometric titration emf measurements at various cathodic current densities (10–100 mA cm−2) were performed to evaluate the stability of the Nd-Sn electrode and corroborate emf values for Nd (in Bi) at T = 873 K. The potential difference between two identical Nd-Sn reference electrodes was measured before/after the electrochemical evaluation for 45 days, and the stability of the cell for the long-term operation was verified. The emf values of Nd (in liquid Bi) titrated at various current densities were consistent at each Nd concentration, demonstrating the reliability of the cell.",

author = "Sanghyeok Im and Smith, {Nathan D.} and Baldivieso, {Stephanie Castro} and Hojong Kim",

note = "Publisher Copyright: {\textcopyright} 2022, The Minerals, Metals & Materials Society.; 8th Symposium on Rare Metal Extraction and Processing held at the TMS Annual Meeting and Exhibition, 2022 ; Conference date: 27-02-2022 Through 03-03-2022",

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doi = "10.1007/978-3-030-92662-5_30",

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Im, S, Smith, ND, Baldivieso, SC & Kim, H 2022, Electrochemical Cell Design for Emf Measurements of Liquid Nd-Bi Alloys via Coulombic Titration in LiCl–KCl–NdCl₃ Electrolyte. in T Ouchi, G Azimi, K Forsberg, H Kim, S Alam, NR Neelameggham, AA Baba & H Peng (eds), Rare Metal Technology, 2022. Minerals, Metals and Materials Series, vol. Part F, Springer Science and Business Media Deutschland GmbH, pp. 317-324, 8th Symposium on Rare Metal Extraction and Processing held at the TMS Annual Meeting and Exhibition, 2022, Anaheim, United States, 2/27/22. https://doi.org/10.1007/978-3-030-92662-5_30

Electrochemical Cell Design for Emf Measurements of Liquid Nd-Bi Alloys via Coulombic Titration in LiCl–KCl–NdCl₃ Electrolyte. / Im, Sanghyeok; Smith, Nathan D.; Baldivieso, Stephanie Castro et al.
Rare Metal Technology, 2022. ed. / Takanari Ouchi; Gisele Azimi; Kerstin Forsberg; Hojong Kim; Shafiq Alam; Neale R. Neelameggham; Alafara Abdullahi Baba; Hong Peng. Springer Science and Business Media Deutschland GmbH, 2022. p. 317-324 (Minerals, Metals and Materials Series; Vol. Part F).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

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T1 - Electrochemical Cell Design for Emf Measurements of Liquid Nd-Bi Alloys via Coulombic Titration in LiCl–KCl–NdCl3 Electrolyte

AU - Im, Sanghyeok

AU - Smith, Nathan D.

AU - Baldivieso, Stephanie Castro

AU - Kim, Hojong

PY - 2022

Y1 - 2022

N2 - Using an electrochemical cell containing a two-phase Nd-Sn alloy (xNd = 0.10) in LiCl–KCl–NdCl3 (1 mol%) as a reference electrode, coulometric titration emf measurements at various cathodic current densities (10–100 mA cm−2) were performed to evaluate the stability of the Nd-Sn electrode and corroborate emf values for Nd (in Bi) at T = 873 K. The potential difference between two identical Nd-Sn reference electrodes was measured before/after the electrochemical evaluation for 45 days, and the stability of the cell for the long-term operation was verified. The emf values of Nd (in liquid Bi) titrated at various current densities were consistent at each Nd concentration, demonstrating the reliability of the cell.

AB - Using an electrochemical cell containing a two-phase Nd-Sn alloy (xNd = 0.10) in LiCl–KCl–NdCl3 (1 mol%) as a reference electrode, coulometric titration emf measurements at various cathodic current densities (10–100 mA cm−2) were performed to evaluate the stability of the Nd-Sn electrode and corroborate emf values for Nd (in Bi) at T = 873 K. The potential difference between two identical Nd-Sn reference electrodes was measured before/after the electrochemical evaluation for 45 days, and the stability of the cell for the long-term operation was verified. The emf values of Nd (in liquid Bi) titrated at various current densities were consistent at each Nd concentration, demonstrating the reliability of the cell.

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T3 - Minerals, Metals and Materials Series

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BT - Rare Metal Technology, 2022

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A2 - Baba, Alafara Abdullahi

A2 - Peng, Hong

PB - Springer Science and Business Media Deutschland GmbH

T2 - 8th Symposium on Rare Metal Extraction and Processing held at the TMS Annual Meeting and Exhibition, 2022

Y2 - 27 February 2022 through 3 March 2022

ER -

Im S, Smith ND, Baldivieso SC, Kim H. Electrochemical Cell Design for Emf Measurements of Liquid Nd-Bi Alloys via Coulombic Titration in LiCl–KCl–NdCl₃ Electrolyte. In Ouchi T, Azimi G, Forsberg K, Kim H, Alam S, Neelameggham NR, Baba AA, Peng H, editors, Rare Metal Technology, 2022. Springer Science and Business Media Deutschland GmbH. 2022. p. 317-324. (Minerals, Metals and Materials Series). doi: 10.1007/978-3-030-92662-5_30