Electrode-confined catalyst systems for use in optical-to-chemical energy conversion

Karen A. Daube; D. Jed Harrison; Thomas E. Mallouk; Antonio J. Ricco; Shuchi Chao; Mark S. Wrighton; William A. Hendrickson; Arnold J. Drube

doi:10.1016/0047-2670(85)87062-3

Electrode-confined catalyst systems for use in optical-to-chemical energy conversion

Karen A. Daube
, D. Jed Harrison
, Thomas E. Mallouk
, Antonio J. Ricco
, Shuchi Chao
, Mark S. Wrighton
, William A. Hendrickson
, Arnold J. Drube

Chemistry

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

Catalysis of multiple-electron transfer fuel-forming redox reactions at illuminated semiconductor-liquid electrolyte interfaces is important in achieving efficient optical energy conversion. The characterization of redox polymer-noble metal combinations as catalysts for the reduction of H₂O and aqueous CO₂ is described in this article. Emphasis is on the demonstration of rational synthetic methods applied to interfaces and the correlation of surface structure and function.

Original language	English (US)
Pages (from-to)	71-88
Number of pages	18
Journal	Journal of Photochemistry
Volume	29
Issue number	1-2
DOIs	https://doi.org/10.1016/0047-2670(85)87062-3
State	Published - May 1985

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@article{f932cf50e068421d9ce7e7fa49e874e3,

title = "Electrode-confined catalyst systems for use in optical-to-chemical energy conversion",

abstract = "Catalysis of multiple-electron transfer fuel-forming redox reactions at illuminated semiconductor-liquid electrolyte interfaces is important in achieving efficient optical energy conversion. The characterization of redox polymer-noble metal combinations as catalysts for the reduction of H2O and aqueous CO2 is described in this article. Emphasis is on the demonstration of rational synthetic methods applied to interfaces and the correlation of surface structure and function.",

author = "Daube, \{Karen A.\} and Harrison, \{D. Jed\} and Mallouk, \{Thomas E.\} and Ricco, \{Antonio J.\} and Shuchi Chao and Wrighton, \{Mark S.\} and Hendrickson, \{William A.\} and Drube, \{Arnold J.\}",

note = "Funding Information: We are grateful for support from the U.S. Department of Energy, Office of Basic Energy Sciences, Division of Chemical Sciences. D.J.H. acknowledges partial support as a National Science and Engineering Research Council Predoctoral Fellow (1980 - 1984). The use of the Central Facilities of the Massachusetts Institute of Technology Center for Materials Science and Engineering is appreciated.",

year = "1985",

month = may,

doi = "10.1016/0047-2670(85)87062-3",

language = "English (US)",

volume = "29",

pages = "71--88",

journal = "Journal of Photochemistry",

issn = "0047-2670",

publisher = "Elsevier Sequoia",

number = "1-2",

}

TY - JOUR

T1 - Electrode-confined catalyst systems for use in optical-to-chemical energy conversion

AU - Daube, Karen A.

AU - Harrison, D. Jed

AU - Mallouk, Thomas E.

AU - Ricco, Antonio J.

AU - Chao, Shuchi

AU - Wrighton, Mark S.

AU - Hendrickson, William A.

AU - Drube, Arnold J.

N1 - Funding Information: We are grateful for support from the U.S. Department of Energy, Office of Basic Energy Sciences, Division of Chemical Sciences. D.J.H. acknowledges partial support as a National Science and Engineering Research Council Predoctoral Fellow (1980 - 1984). The use of the Central Facilities of the Massachusetts Institute of Technology Center for Materials Science and Engineering is appreciated.

PY - 1985/5

Y1 - 1985/5

N2 - Catalysis of multiple-electron transfer fuel-forming redox reactions at illuminated semiconductor-liquid electrolyte interfaces is important in achieving efficient optical energy conversion. The characterization of redox polymer-noble metal combinations as catalysts for the reduction of H2O and aqueous CO2 is described in this article. Emphasis is on the demonstration of rational synthetic methods applied to interfaces and the correlation of surface structure and function.

AB - Catalysis of multiple-electron transfer fuel-forming redox reactions at illuminated semiconductor-liquid electrolyte interfaces is important in achieving efficient optical energy conversion. The characterization of redox polymer-noble metal combinations as catalysts for the reduction of H2O and aqueous CO2 is described in this article. Emphasis is on the demonstration of rational synthetic methods applied to interfaces and the correlation of surface structure and function.

UR - https://www.scopus.com/pages/publications/0043186152

UR - https://www.scopus.com/pages/publications/0043186152#tab=citedBy

U2 - 10.1016/0047-2670(85)87062-3

DO - 10.1016/0047-2670(85)87062-3

M3 - Article

AN - SCOPUS:0043186152

SN - 0047-2670

VL - 29

SP - 71

EP - 88

JO - Journal of Photochemistry

JF - Journal of Photochemistry

IS - 1-2

ER -

Electrode-confined catalyst systems for use in optical-to-chemical energy conversion

Abstract

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