Electron transport in multiterminal molecular devices: A density functional theory study

Kamal K. Saha, Wenchang Lu, J. Bernholc, Vincent Meunier

Research output: Contribution to journalArticlepeer-review

18 Scopus citations

Abstract

The electron transport properties of a four-terminal molecular device are computed within the framework of density functional theory and nonequilibrium Keldysh theory. The additional two terminals lead to new properties, including a pronounced negative differential resistance not present in a two-terminal setup, and a pseudogating effect. In general, quantum interference between the four terminals and the central molecule leads to a complex nonlinear behavior of the current, which depends on the alignment of individual molecular states under bias and their coupling to the leads.

Original languageEnglish (US)
Article number125420
JournalPhysical Review B - Condensed Matter and Materials Physics
Volume81
Issue number12
DOIs
StatePublished - Mar 18 2010

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics

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