Abstract
The combined effects of energy and free volume are considered in the self-diffusion of trace amounts of solvents in amorphous polymers. A method for the determination of the parameters of the free-volume theory of transport is discussed. The ability of the combined energy and free-volume formulation to describe the temperature dependence of the self-diffusion process is evaluated using diffusion data both above and below the polymer glass transition temperature.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 1277-1281 |
| Number of pages | 5 |
| Journal | Macromolecules |
| Volume | 26 |
| Issue number | 6 |
| DOIs | |
| State | Published - 1993 |
All Science Journal Classification (ASJC) codes
- Organic Chemistry
- Polymers and Plastics
- Inorganic Chemistry
- Materials Chemistry
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