Enhanced detection of explosives by turn-on resonance Raman upon host-guest complexation in solution and the solid state

Edward H. Witlicki; Steffen Bähring; Carsten Johnsen; Marta V. Solano; Kent A. Nielsen; Daniel W. Silverstein; Craig W. Marlatt; Lasse Jensen; Jan O. Jeppesen; Amar H. Flood

doi:10.1039/c7cc06517e

Enhanced detection of explosives by turn-on resonance Raman upon host-guest complexation in solution and the solid state

Edward H. Witlicki
, Steffen Bähring
, Carsten Johnsen
, Marta V. Solano
, Kent A. Nielsen
, Daniel W. Silverstein
, Craig W. Marlatt
, Lasse Jensen
, Jan O. Jeppesen
, Amar H. Flood

Chemistry

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

The recognition of nitroaromatic explosives by a tetrakis-tetrathiafulvalene-calix[4]pyrrole receptor (TTF-C[4]P) yields a "turn on" and fingerprinting response in the resonance Raman scattering observed in solution and the solid state. Intensity changes in nitro vibrations with analyte complexation occur via a mechanism of resonance between the 785 nm laser line and the strongly absorbing charge-transfer chromophore arising from the complex between electron-donating TTF-C[4]P and electron-accepting nitroaromatic explosives. The addition of chloride forms the Cl^-·TTF-C[4]P complex resetting the system for reuse.

Original language	English (US)
Pages (from-to)	10918-10921
Number of pages	4
Journal	Chemical Communications
Volume	53
Issue number	79
DOIs	https://doi.org/10.1039/c7cc06517e
State	Published - 2017

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c7cc06517e

Cite this

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title = "Enhanced detection of explosives by turn-on resonance Raman upon host-guest complexation in solution and the solid state",

abstract = "The recognition of nitroaromatic explosives by a tetrakis-tetrathiafulvalene-calix[4]pyrrole receptor (TTF-C[4]P) yields a {"}turn on{"} and fingerprinting response in the resonance Raman scattering observed in solution and the solid state. Intensity changes in nitro vibrations with analyte complexation occur via a mechanism of resonance between the 785 nm laser line and the strongly absorbing charge-transfer chromophore arising from the complex between electron-donating TTF-C[4]P and electron-accepting nitroaromatic explosives. The addition of chloride forms the Cl-·TTF-C[4]P complex resetting the system for reuse.",

author = "Witlicki, \{Edward H.\} and Steffen B{\"a}hring and Carsten Johnsen and Solano, \{Marta V.\} and Nielsen, \{Kent A.\} and Silverstein, \{Daniel W.\} and Marlatt, \{Craig W.\} and Lasse Jensen and Jeppesen, \{Jan O.\} and Flood, \{Amar H.\}",

note = "Publisher Copyright: {\textcopyright} 2017 The Royal Society of Chemistry.",

year = "2017",

doi = "10.1039/c7cc06517e",

language = "English (US)",

volume = "53",

pages = "10918--10921",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "79",

}

TY - JOUR

T1 - Enhanced detection of explosives by turn-on resonance Raman upon host-guest complexation in solution and the solid state

AU - Witlicki, Edward H.

AU - Bähring, Steffen

AU - Johnsen, Carsten

AU - Solano, Marta V.

AU - Nielsen, Kent A.

AU - Silverstein, Daniel W.

AU - Marlatt, Craig W.

AU - Jensen, Lasse

AU - Jeppesen, Jan O.

AU - Flood, Amar H.

PY - 2017

Y1 - 2017

N2 - The recognition of nitroaromatic explosives by a tetrakis-tetrathiafulvalene-calix[4]pyrrole receptor (TTF-C[4]P) yields a "turn on" and fingerprinting response in the resonance Raman scattering observed in solution and the solid state. Intensity changes in nitro vibrations with analyte complexation occur via a mechanism of resonance between the 785 nm laser line and the strongly absorbing charge-transfer chromophore arising from the complex between electron-donating TTF-C[4]P and electron-accepting nitroaromatic explosives. The addition of chloride forms the Cl-·TTF-C[4]P complex resetting the system for reuse.

AB - The recognition of nitroaromatic explosives by a tetrakis-tetrathiafulvalene-calix[4]pyrrole receptor (TTF-C[4]P) yields a "turn on" and fingerprinting response in the resonance Raman scattering observed in solution and the solid state. Intensity changes in nitro vibrations with analyte complexation occur via a mechanism of resonance between the 785 nm laser line and the strongly absorbing charge-transfer chromophore arising from the complex between electron-donating TTF-C[4]P and electron-accepting nitroaromatic explosives. The addition of chloride forms the Cl-·TTF-C[4]P complex resetting the system for reuse.

UR - https://www.scopus.com/pages/publications/85030624700

UR - https://www.scopus.com/pages/publications/85030624700#tab=citedBy

U2 - 10.1039/c7cc06517e

DO - 10.1039/c7cc06517e

M3 - Article

C2 - 28929145

AN - SCOPUS:85030624700

SN - 1359-7345

VL - 53

SP - 10918

EP - 10921

JO - Chemical Communications

JF - Chemical Communications

IS - 79

ER -

Enhanced detection of explosives by turn-on resonance Raman upon host-guest complexation in solution and the solid state

Abstract

All Science Journal Classification (ASJC) codes

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