Enhanced hydrogen generation using a saline catholyte in a two chamber microbial electrolysis cell

Joo Youn Nam, Bruce E. Logan

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73 Scopus citations


High rates of hydrogen gas production were achieved in a two chamber microbial electrolysis cell (MEC) without a catholyte phosphate buffer by using a saline catholyte solution and a cathode constructed around a stainless steel mesh current collector. Using the non-buffered salt solution (68 mM NaCl) produced the highest current density of 131 ± 12 A/m3, hydrogen yield of 3.2 ± 0.3 mol H2/mol acetate, and gas production rate of 1.6 ± 0.2 m3 H2/m 3·d, compared to MECs with catholytes externally sparged with CO2 or containing a phosphate buffer. The salinity of the catholyte achieved a high solution conductivity, and therefore the electrode spacing did not appreciably affect performance. The coulombic efficiency with the cathode placed near the membrane separating the chambers was 83 ± 4%, similar to that obtained with the cathode placed more distant from the membrane (84 ± 4%). Using a carbon cloth cathode instead of the stainless steel mesh cathode did not significantly affect performance, with all reactor configurations producing similar performance in terms of total gas volume, COD removal, rcat and overall energy recovery. These results show MEC performance can be improved by using a saline catholyte without pH control.

Original languageEnglish (US)
Pages (from-to)15105-15110
Number of pages6
JournalInternational Journal of Hydrogen Energy
Issue number23
StatePublished - Nov 2011

All Science Journal Classification (ASJC) codes

  • Renewable Energy, Sustainability and the Environment
  • Fuel Technology
  • Condensed Matter Physics
  • Energy Engineering and Power Technology


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