Epoxidization of allyl chloride by combined oxidation with ethylbenzene on layered compounds of graphite with transition-metal chlorides

N. I. Kovtyukhova; V. M. Belousov; Yu N. Novikov; M. E. Vol'pin

doi:10.1007/BF00954271

Epoxidization of allyl chloride by combined oxidation with ethylbenzene on layered compounds of graphite with transition-metal chlorides

N. I. Kovtyukhova, V. M. Belousov, Yu N. Novikov, M. E. Vol'pin

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

1. We have shown that allyl chloride can be epoxidized by molecular oxygen as a result of combined oxidation with ethylbenzene over a catalyst system composed of LGC-MnCl₂ and LGC-MoCl₅. 2. We have shown that LGC containing Mo, W, and Mn chlorides catalyze the epoxidization of allyl chloride by tert-butyl and ethylbenzene hydroperoxides.

Original language	English (US)
Pages (from-to)	1566-1570
Number of pages	5
Journal	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume	32
Issue number	8
DOIs	https://doi.org/10.1007/BF00954271
State	Published - Aug 1983

All Science Journal Classification (ASJC) codes

General Chemistry

Access to Document

10.1007/BF00954271

Cite this

@article{92ba35600f474ba1b9bb6cbd757b43e1,

title = "Epoxidization of allyl chloride by combined oxidation with ethylbenzene on layered compounds of graphite with transition-metal chlorides",

abstract = "1. We have shown that allyl chloride can be epoxidized by molecular oxygen as a result of combined oxidation with ethylbenzene over a catalyst system composed of LGC-MnCl2 and LGC-MoCl5. 2. We have shown that LGC containing Mo, W, and Mn chlorides catalyze the epoxidization of allyl chloride by tert-butyl and ethylbenzene hydroperoxides.",

author = "Kovtyukhova, {N. I.} and Belousov, {V. M.} and Novikov, {Yu N.} and Vol'pin, {M. E.}",

year = "1983",

month = aug,

doi = "10.1007/BF00954271",

language = "English (US)",

volume = "32",

pages = "1566--1570",

journal = "Bulletin of the Academy of Sciences of the USSR Division of Chemical Science",

issn = "0568-5230",

publisher = "Springer New York",

number = "8",

}

Epoxidization of allyl chloride by combined oxidation with ethylbenzene on layered compounds of graphite with transition-metal chlorides. / Kovtyukhova, N. I.; Belousov, V. M.; Novikov, Yu N. et al.
In: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, Vol. 32, No. 8, 08.1983, p. 1566-1570.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Epoxidization of allyl chloride by combined oxidation with ethylbenzene on layered compounds of graphite with transition-metal chlorides

AU - Kovtyukhova, N. I.

AU - Belousov, V. M.

AU - Novikov, Yu N.

AU - Vol'pin, M. E.

PY - 1983/8

Y1 - 1983/8

N2 - 1. We have shown that allyl chloride can be epoxidized by molecular oxygen as a result of combined oxidation with ethylbenzene over a catalyst system composed of LGC-MnCl2 and LGC-MoCl5. 2. We have shown that LGC containing Mo, W, and Mn chlorides catalyze the epoxidization of allyl chloride by tert-butyl and ethylbenzene hydroperoxides.

AB - 1. We have shown that allyl chloride can be epoxidized by molecular oxygen as a result of combined oxidation with ethylbenzene over a catalyst system composed of LGC-MnCl2 and LGC-MoCl5. 2. We have shown that LGC containing Mo, W, and Mn chlorides catalyze the epoxidization of allyl chloride by tert-butyl and ethylbenzene hydroperoxides.

UR - http://www.scopus.com/inward/record.url?scp=34250152403&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=34250152403&partnerID=8YFLogxK

U2 - 10.1007/BF00954271

DO - 10.1007/BF00954271

M3 - Article

AN - SCOPUS:34250152403

SN - 0568-5230

VL - 32

SP - 1566

EP - 1570

JO - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

JF - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

IS - 8

ER -

Epoxidization of allyl chloride by combined oxidation with ethylbenzene on layered compounds of graphite with transition-metal chlorides

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this