Equation-of-state model for temperature-responsive polymers with tunable response onset

E. Manias; Alexei M. Kisselev

doi:10.1063/1.2827051

Equation-of-state model for temperature-responsive polymers with tunable response onset

E. Manias, Alexei M. Kisselev

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Abstract

The phase behavior of aqueous solutions of temperature-responsive (ethylene oxide)/ethylene copolymers with tunable lower critical solution temperatures (LCST) is explored using an equation of state approach. The LCST in water of these polymers is tailored by their chemical composition, specifically by the balance of hydrophilic to hydrophobic groups in the polymer. The general formalism of the lattice-fluid with hydrogen-bonding theory, adjusted here to account for multiple types of hydrogen bonds, is employed, and the theoretical predictions are compared with experimental systems. The developed theoretical model is shown to be effective in describing the phase behavior of these systems, and the model parameters seem to be transferable between different homologous copolymer series.

Original language	English (US)
Title of host publication	Computational Methods in Science and Engineering - Theory and Computation
Subtitle of host publication	Old Problems and New Challenges, Lectures Presented at the Int. Conf. Computational Methods in Sci. Eng. 2007 ICCMSE 2007
Pages	636-651
Number of pages	16
Edition	1
DOIs	https://doi.org/10.1063/1.2827051
State	Published - 2007
Event	5th International Conference on Computational Methods in Science and Engineering, ICCMSE 2007 - Corfu, Greece Duration: Sep 25 2007 → Sep 30 2007

Publication series

Name	AIP Conference Proceedings
Number	1
Volume	963
ISSN (Print)	0094-243X
ISSN (Electronic)	1551-7616

Other

Other	5th International Conference on Computational Methods in Science and Engineering, ICCMSE 2007
Country/Territory	Greece
City	Corfu
Period	9/25/07 → 9/30/07

All Science Journal Classification (ASJC) codes

General Physics and Astronomy

Access to Document

10.1063/1.2827051

Cite this

Manias, E., & Kisselev, A. M. (2007). Equation-of-state model for temperature-responsive polymers with tunable response onset. In Computational Methods in Science and Engineering - Theory and Computation: Old Problems and New Challenges, Lectures Presented at the Int. Conf. Computational Methods in Sci. Eng. 2007 ICCMSE 2007 (1 ed., pp. 636-651). (AIP Conference Proceedings; Vol. 963, No. 1). https://doi.org/10.1063/1.2827051

Manias, E. ; Kisselev, Alexei M. / Equation-of-state model for temperature-responsive polymers with tunable response onset. Computational Methods in Science and Engineering - Theory and Computation: Old Problems and New Challenges, Lectures Presented at the Int. Conf. Computational Methods in Sci. Eng. 2007 ICCMSE 2007. 1. ed. 2007. pp. 636-651 (AIP Conference Proceedings; 1).

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title = "Equation-of-state model for temperature-responsive polymers with tunable response onset",

abstract = "The phase behavior of aqueous solutions of temperature-responsive (ethylene oxide)/ethylene copolymers with tunable lower critical solution temperatures (LCST) is explored using an equation of state approach. The LCST in water of these polymers is tailored by their chemical composition, specifically by the balance of hydrophilic to hydrophobic groups in the polymer. The general formalism of the lattice-fluid with hydrogen-bonding theory, adjusted here to account for multiple types of hydrogen bonds, is employed, and the theoretical predictions are compared with experimental systems. The developed theoretical model is shown to be effective in describing the phase behavior of these systems, and the model parameters seem to be transferable between different homologous copolymer series.",

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series = "AIP Conference Proceedings",

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Manias, E & Kisselev, AM 2007, Equation-of-state model for temperature-responsive polymers with tunable response onset. in Computational Methods in Science and Engineering - Theory and Computation: Old Problems and New Challenges, Lectures Presented at the Int. Conf. Computational Methods in Sci. Eng. 2007 ICCMSE 2007. 1 edn, AIP Conference Proceedings, no. 1, vol. 963, pp. 636-651, 5th International Conference on Computational Methods in Science and Engineering, ICCMSE 2007, Corfu, Greece, 9/25/07. https://doi.org/10.1063/1.2827051

Equation-of-state model for temperature-responsive polymers with tunable response onset. / Manias, E.; Kisselev, Alexei M.
Computational Methods in Science and Engineering - Theory and Computation: Old Problems and New Challenges, Lectures Presented at the Int. Conf. Computational Methods in Sci. Eng. 2007 ICCMSE 2007. 1. ed. 2007. p. 636-651 (AIP Conference Proceedings; Vol. 963, No. 1).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

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AB - The phase behavior of aqueous solutions of temperature-responsive (ethylene oxide)/ethylene copolymers with tunable lower critical solution temperatures (LCST) is explored using an equation of state approach. The LCST in water of these polymers is tailored by their chemical composition, specifically by the balance of hydrophilic to hydrophobic groups in the polymer. The general formalism of the lattice-fluid with hydrogen-bonding theory, adjusted here to account for multiple types of hydrogen bonds, is employed, and the theoretical predictions are compared with experimental systems. The developed theoretical model is shown to be effective in describing the phase behavior of these systems, and the model parameters seem to be transferable between different homologous copolymer series.

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Manias E, Kisselev AM. Equation-of-state model for temperature-responsive polymers with tunable response onset. In Computational Methods in Science and Engineering - Theory and Computation: Old Problems and New Challenges, Lectures Presented at the Int. Conf. Computational Methods in Sci. Eng. 2007 ICCMSE 2007. 1 ed. 2007. p. 636-651. (AIP Conference Proceedings; 1). doi: 10.1063/1.2827051

Equation-of-state model for temperature-responsive polymers with tunable response onset

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