TY - JOUR
T1 - (Ethanolato)[2,3,7,8,12,13,17,18-octa-ethylporphyrinato(2-)]iron(III)
AU - Cheng, Lin
AU - Xu, Nan
AU - Powell, Douglas R.
AU - Richter-Addo, George B.
PY - 2010/11
Y1 - 2010/11
N2 - The title compound, [Fe(C2H5O)(C36H 44N4)], contains a five-coordinate iron-porphyrin complex with an axial eth-oxy ligand. The iron(III) atom is displaced by 0.504 (2) Å towards the eth-oxy ligand from the 24-atom mean plane of the porphyrin. The average Fe - Np distance is 2.078 (2) Å and the Fe - O distance is 1.8232 (18) Å. The eth-oxy C atoms are disordered in a 0.581 (12):0.419 (12) ratio. The bond angles of the Fe - O - C linkage are 128.6 (3) and 130.4 (3)°, respectively, for the major and minor occupancy C atoms.
AB - The title compound, [Fe(C2H5O)(C36H 44N4)], contains a five-coordinate iron-porphyrin complex with an axial eth-oxy ligand. The iron(III) atom is displaced by 0.504 (2) Å towards the eth-oxy ligand from the 24-atom mean plane of the porphyrin. The average Fe - Np distance is 2.078 (2) Å and the Fe - O distance is 1.8232 (18) Å. The eth-oxy C atoms are disordered in a 0.581 (12):0.419 (12) ratio. The bond angles of the Fe - O - C linkage are 128.6 (3) and 130.4 (3)°, respectively, for the major and minor occupancy C atoms.
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U2 - 10.1107/S1600536810041024
DO - 10.1107/S1600536810041024
M3 - Article
C2 - 21588876
AN - SCOPUS:78650959479
SN - 1600-5368
VL - 66
SP - m1458
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 11
ER -