@article{bbaba642462f4eb69f7355b5d1d50da0,
title = "Ethylene Oligomerization to Select Oligomers on Ni-ETS-10",
abstract = "The oligomerization of short alkenes (ethylene and propylene) can be used for producing commodity chemicals. Various catalysts have been used for alkene oligomerization, among which ordered microporous catalysts are thermally and mechanically stable and are already established for large-scale industrial applications. In this work, we demonstrate ethylene oligomerization reaction on a microporous titanosilicate ETS-10 (Engelhard Titanosiliate-10) exchanged with Ni2+ (Ni-ETS-10). We demonstrate a template-free and fluoride-free ETS-10 synthesis method that does not produce impurities commonly seen in hydrothermal ETS-10 synthesis. Ni-ETS-10 showed high C2 conversion rate, high selectivity to C4 and high stability comparing to other microporous catalysts investigated in this work for ethylene oligomerization reaction.",
author = "Jay Thakkar and Xinyang Yin and Xueyi Zhang",
note = "Funding Information: The authors acknowledge the financial support from the Department of Chemical Engineering and the Institute for Natural Gas Research (INGaR) at the Pennsylvania State University. X.Z. acknowledges financial support from the John J. and Jean M. Brennan Clean Energy Early Career Professorship. Materials characterization was performed at the Materials Characterization Laboratory, which is a partner in the National Nanotechnology Infrastructure Network (NNIN) and the Materials Research Facilities Network (MRFN), supported by the U.S. National Science Foundation (award DMR-1420620). A U.S. patent application by X.Z. and J.T. was filed on March 5, 2018 (Application No. 62/ 638,366). Funding Information: The authors acknowledge the financial support from the Department of Chemical Engineering and the Institute for Natural Gas Research (INGaR) at the Pennsylvania State University. X.Z. acknowledges financial support from the John J. and Jean M. Brennan Clean Energy Early Career Professorship. Materials characterization was performed at the Materials Characterization Laboratory, which is a partner in the National Nanotechnology Infrastructure Network (NNIN) and the Materials Research Facilities Network (MRFN), supported by the U.S. National Science Foundation (award DMR-1420620). A U.S. patent application by X.Z. and J.T. was filed on March 5, 2018 (Application No. 62/638,366). Publisher Copyright: {\textcopyright} 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim",
year = "2018",
month = oct,
day = "9",
doi = "10.1002/cctc.201800650",
language = "English (US)",
volume = "10",
pages = "4234--4237",
journal = "ChemCatChem",
issn = "1867-3880",
publisher = "Wiley - VCH Verlag GmbH & CO. KGaA",
number = "19",
}