EXAFS Structural Study of FX, the Low-Potential Fe-S Center in Photosystem I

Ann E. McDermott; Vittal K. Yachandra; Ronald D. Guiles; Kenneth Sauer; Melvin P. Klein; Kevin G. Parrett; John H. Golbeck

doi:10.1021/bi00446a013

EXAFS Structural Study of FX, the Low-Potential Fe-S Center in Photosystem I

Ann E. McDermott
, Vittal K. Yachandra
, Ronald D. Guiles
, Kenneth Sauer
, Melvin P. Klein
, Kevin G. Parrett
, John H. Golbeck

Biochemistry & Molecular Biology

Research output: Contribution to journal › Article › peer-review

28 Scopus citations

Abstract

We present iron extended X-ray absorption fine structure (EXAFS) spectra of a photosystem I core preparation containing F_X, the very low potential iron–sulfur cluster in photosystem I. The preparation lacks F_A and F_B. The amplitude of Fe–Fe backscattering in the EXAFS spectrum indicates that F_X may be a [4Fe-4S] cluster and is not a [2Fe-2S] cluster or clusters.

Original language	English (US)
Pages (from-to)	8056-8059
Number of pages	4
Journal	Biochemistry
Volume	28
Issue number	20
DOIs	https://doi.org/10.1021/bi00446a013
State	Published - Jan 1 1989

All Science Journal Classification (ASJC) codes

Biochemistry

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10.1021/bi00446a013

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title = "EXAFS Structural Study of FX, the Low-Potential Fe-S Center in Photosystem I",

abstract = "We present iron extended X-ray absorption fine structure (EXAFS) spectra of a photosystem I core preparation containing FX, the very low potential iron–sulfur cluster in photosystem I. The preparation lacks FA and FB. The amplitude of Fe–Fe backscattering in the EXAFS spectrum indicates that FX may be a [4Fe-4S] cluster and is not a [2Fe-2S] cluster or clusters.",

author = "McDermott, \{Ann E.\} and Yachandra, \{Vittal K.\} and Guiles, \{Ronald D.\} and Kenneth Sauer and Klein, \{Melvin P.\} and Parrett, \{Kevin G.\} and Golbeck, \{John H.\}",

year = "1989",

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doi = "10.1021/bi00446a013",

language = "English (US)",

volume = "28",

pages = "8056--8059",

journal = "Biochemistry",

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publisher = "American Chemical Society",

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T1 - EXAFS Structural Study of FX, the Low-Potential Fe-S Center in Photosystem I

AU - McDermott, Ann E.

AU - Yachandra, Vittal K.

AU - Guiles, Ronald D.

AU - Sauer, Kenneth

AU - Klein, Melvin P.

AU - Parrett, Kevin G.

AU - Golbeck, John H.

PY - 1989/1/1

Y1 - 1989/1/1

N2 - We present iron extended X-ray absorption fine structure (EXAFS) spectra of a photosystem I core preparation containing FX, the very low potential iron–sulfur cluster in photosystem I. The preparation lacks FA and FB. The amplitude of Fe–Fe backscattering in the EXAFS spectrum indicates that FX may be a [4Fe-4S] cluster and is not a [2Fe-2S] cluster or clusters.

AB - We present iron extended X-ray absorption fine structure (EXAFS) spectra of a photosystem I core preparation containing FX, the very low potential iron–sulfur cluster in photosystem I. The preparation lacks FA and FB. The amplitude of Fe–Fe backscattering in the EXAFS spectrum indicates that FX may be a [4Fe-4S] cluster and is not a [2Fe-2S] cluster or clusters.

UR - https://www.scopus.com/pages/publications/0024960680

UR - https://www.scopus.com/pages/publications/0024960680#tab=citedBy

U2 - 10.1021/bi00446a013

DO - 10.1021/bi00446a013

M3 - Article

C2 - 2690931

AN - SCOPUS:0024960680

SN - 0006-2960

VL - 28

SP - 8056

EP - 8059

JO - Biochemistry

JF - Biochemistry

IS - 20

ER -

EXAFS Structural Study of FX, the Low-Potential Fe-S Center in Photosystem I

Abstract

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