Excimer Formation in the Interlayer Region of Arene-Derivatized Zirconium Phosphonates

Jay C. Amicangelo; Willem R. Leenstra

doi:10.1021/ja030483h

Excimer Formation in the Interlayer Region of Arene-Derivatized Zirconium Phosphonates

Jay C. Amicangelo, Willem R. Leenstra

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31 Scopus citations

Abstract

Photophysical investigations are reported for two arene-derivatized zirconium phosphonates (layered solids). The chromophore groups that are attached within the interlayer region of these materials are seen to form excimer pairs. Whereas the naphthalene-containing system exhibits both monomer and excimer fluorescence, the potentially greater overlap of chromophores for the system containing anthracene-pendant groups causes that compound to only show excimer fluorescence.

Original language	English (US)
Pages (from-to)	14698-14699
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	125
Issue number	48
DOIs	https://doi.org/10.1021/ja030483h
State	Published - Dec 3 2003

All Science Journal Classification (ASJC) codes

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja030483h

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title = "Excimer Formation in the Interlayer Region of Arene-Derivatized Zirconium Phosphonates",

abstract = "Photophysical investigations are reported for two arene-derivatized zirconium phosphonates (layered solids). The chromophore groups that are attached within the interlayer region of these materials are seen to form excimer pairs. Whereas the naphthalene-containing system exhibits both monomer and excimer fluorescence, the potentially greater overlap of chromophores for the system containing anthracene-pendant groups causes that compound to only show excimer fluorescence.",

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year = "2003",

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AU - Leenstra, Willem R.

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Y1 - 2003/12/3

N2 - Photophysical investigations are reported for two arene-derivatized zirconium phosphonates (layered solids). The chromophore groups that are attached within the interlayer region of these materials are seen to form excimer pairs. Whereas the naphthalene-containing system exhibits both monomer and excimer fluorescence, the potentially greater overlap of chromophores for the system containing anthracene-pendant groups causes that compound to only show excimer fluorescence.

AB - Photophysical investigations are reported for two arene-derivatized zirconium phosphonates (layered solids). The chromophore groups that are attached within the interlayer region of these materials are seen to form excimer pairs. Whereas the naphthalene-containing system exhibits both monomer and excimer fluorescence, the potentially greater overlap of chromophores for the system containing anthracene-pendant groups causes that compound to only show excimer fluorescence.

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Excimer Formation in the Interlayer Region of Arene-Derivatized Zirconium Phosphonates

Abstract

All Science Journal Classification (ASJC) codes

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