Abstract
We recently measured complete time- and frequency-resolved fluorescence spectra of 7AI in a number of alcohols and showed how past ambiguities could be traced to the fact that the ″normal″ fluorescence undergoes a time-dependent Stokes shift. This Stokes shift is a result of solvation energy relaxation and is not directly connected to the population kinetics of the reaction. We also have performed an extensive series of measurements of the proton transfer rate of 7AI as a function of alcohol, temperature, and solvent deuteration.
| Original language | English (US) |
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| Title of host publication | Ultrafast Phenomena VIII |
| Publisher | Publ by Springer-Verlag GmbH & Company KG |
| Pages | 624-625 |
| Number of pages | 2 |
| Edition | 55 |
| ISBN (Print) | 3540564756 |
| State | Published - 1993 |
| Event | Proceedings of the 8th International Conference on Ultrafast Phenomena - Antibes Juan-Les-Pins, France Duration: Jun 8 1992 → Jun 12 1992 |
Conference
| Conference | Proceedings of the 8th International Conference on Ultrafast Phenomena |
|---|---|
| City | Antibes Juan-Les-Pins, France |
| Period | 6/8/92 → 6/12/92 |
All Science Journal Classification (ASJC) codes
- Physical and Theoretical Chemistry