Exploring the exciton dissociation process at a donor-acceptor heterojunction in both time and space via an induced Stark shift

Noel Christopher Giebink; Barry P. Rand; David Cheyns; Jan Genoe

doi:10.1117/12.924154

Exploring the exciton dissociation process at a donor-acceptor heterojunction in both time and space via an induced Stark shift

Noel Christopher Giebink
, Barry P. Rand
, David Cheyns
, Jan Genoe

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Abstract

The dissociation of excitons at a donor-acceptor interface in organic photovoltaic devices is an important but poorly understood process that takes place over multiple length and time scales. Here, we introduce a method to resolve photoinduced charge movement at an organic heterojunction in both time and space through observation of the Stark shift induced in a nearby J-aggregate probe layer. Using ultrafast transient absorption measurements, we show that this technique provides an opportunity to quantify the recombination and separation dynamics of geminate charge pairs over the entire sub-picosecond to millisecond range of relevant time scales.

Original language	English (US)
Title of host publication	Organic Photonics V
DOIs	https://doi.org/10.1117/12.924154
State	Published - 2012
Event	Organic Photonics V - Brussels, Belgium Duration: Apr 16 2012 → Apr 18 2012

Publication series

Name	Proceedings of SPIE - The International Society for Optical Engineering
Volume	8435
ISSN (Print)	0277-786X

Other

Other	Organic Photonics V
Country/Territory	Belgium
City	Brussels
Period	4/16/12 → 4/18/12

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Applied Mathematics
Electrical and Electronic Engineering
Computer Science Applications

Access to Document

10.1117/12.924154

Cite this

@inproceedings{20df41530b2a456d9c63932dac97d87b,

title = "Exploring the exciton dissociation process at a donor-acceptor heterojunction in both time and space via an induced Stark shift",

abstract = "The dissociation of excitons at a donor-acceptor interface in organic photovoltaic devices is an important but poorly understood process that takes place over multiple length and time scales. Here, we introduce a method to resolve photoinduced charge movement at an organic heterojunction in both time and space through observation of the Stark shift induced in a nearby J-aggregate probe layer. Using ultrafast transient absorption measurements, we show that this technique provides an opportunity to quantify the recombination and separation dynamics of geminate charge pairs over the entire sub-picosecond to millisecond range of relevant time scales.",

author = "Giebink, \{Noel Christopher\} and Rand, \{Barry P.\} and David Cheyns and Jan Genoe",

year = "2012",

doi = "10.1117/12.924154",

language = "English (US)",

isbn = "9780819491275",

series = "Proceedings of SPIE - The International Society for Optical Engineering",

booktitle = "Organic Photonics V",

note = "Organic Photonics V ; Conference date: 16-04-2012 Through 18-04-2012",

}

Giebink, NC, Rand, BP, Cheyns, D & Genoe, J 2012, Exploring the exciton dissociation process at a donor-acceptor heterojunction in both time and space via an induced Stark shift. in Organic Photonics V., 84350L, Proceedings of SPIE - The International Society for Optical Engineering, vol. 8435, Organic Photonics V, Brussels, Belgium, 4/16/12. https://doi.org/10.1117/12.924154

Exploring the exciton dissociation process at a donor-acceptor heterojunction in both time and space via an induced Stark shift. / Giebink, Noel Christopher; Rand, Barry P.; Cheyns, David et al.
Organic Photonics V. 2012. 84350L (Proceedings of SPIE - The International Society for Optical Engineering; Vol. 8435).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

TY - GEN

T1 - Exploring the exciton dissociation process at a donor-acceptor heterojunction in both time and space via an induced Stark shift

AU - Giebink, Noel Christopher

AU - Rand, Barry P.

AU - Cheyns, David

AU - Genoe, Jan

PY - 2012

Y1 - 2012

N2 - The dissociation of excitons at a donor-acceptor interface in organic photovoltaic devices is an important but poorly understood process that takes place over multiple length and time scales. Here, we introduce a method to resolve photoinduced charge movement at an organic heterojunction in both time and space through observation of the Stark shift induced in a nearby J-aggregate probe layer. Using ultrafast transient absorption measurements, we show that this technique provides an opportunity to quantify the recombination and separation dynamics of geminate charge pairs over the entire sub-picosecond to millisecond range of relevant time scales.

AB - The dissociation of excitons at a donor-acceptor interface in organic photovoltaic devices is an important but poorly understood process that takes place over multiple length and time scales. Here, we introduce a method to resolve photoinduced charge movement at an organic heterojunction in both time and space through observation of the Stark shift induced in a nearby J-aggregate probe layer. Using ultrafast transient absorption measurements, we show that this technique provides an opportunity to quantify the recombination and separation dynamics of geminate charge pairs over the entire sub-picosecond to millisecond range of relevant time scales.

UR - https://www.scopus.com/pages/publications/84862270952

UR - https://www.scopus.com/pages/publications/84862270952#tab=citedBy

U2 - 10.1117/12.924154

DO - 10.1117/12.924154

M3 - Conference contribution

AN - SCOPUS:84862270952

SN - 9780819491275

T3 - Proceedings of SPIE - The International Society for Optical Engineering

BT - Organic Photonics V

T2 - Organic Photonics V

Y2 - 16 April 2012 through 18 April 2012

ER -

Exploring the exciton dissociation process at a donor-acceptor heterojunction in both time and space via an induced Stark shift

Abstract

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All Science Journal Classification (ASJC) codes

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