Extending pummerer reaction chemistry. Synthesis of (±)- dibromophakellstatin by oxidative cyclization of an imidazole derivative

Ken S. Feldman; Amanda P. Skoumbourdis

doi:10.1021/ol0500113

Extending pummerer reaction chemistry. Synthesis of (±)- dibromophakellstatin by oxidative cyclization of an imidazole derivative

Ken S. Feldman, Amanda P. Skoumbourdis

Chemistry

Research output: Contribution to journal › Article › peer-review

73 Scopus citations

Abstract

(Chemical Equation Presented) The diastereoselective oxidative cyclization of a dihydrooroidin derivative is reported. The thioimidate product formed by application of a new variant of the Pummerer reaction serves as a precursor to dibromophakellstatin.

Original language	English (US)
Pages (from-to)	929-931
Number of pages	3
Journal	Organic Letters
Volume	7
Issue number	5
DOIs	https://doi.org/10.1021/ol0500113
State	Published - Mar 3 2005

All Science Journal Classification (ASJC) codes

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol0500113

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title = "Extending pummerer reaction chemistry. Synthesis of (±)- dibromophakellstatin by oxidative cyclization of an imidazole derivative",

abstract = "(Chemical Equation Presented) The diastereoselective oxidative cyclization of a dihydrooroidin derivative is reported. The thioimidate product formed by application of a new variant of the Pummerer reaction serves as a precursor to dibromophakellstatin.",

author = "Feldman, {Ken S.} and Skoumbourdis, {Amanda P.}",

year = "2005",

month = mar,

day = "3",

doi = "10.1021/ol0500113",

language = "English (US)",

volume = "7",

pages = "929--931",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

number = "5",

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AU - Feldman, Ken S.

AU - Skoumbourdis, Amanda P.

PY - 2005/3/3

Y1 - 2005/3/3

N2 - (Chemical Equation Presented) The diastereoselective oxidative cyclization of a dihydrooroidin derivative is reported. The thioimidate product formed by application of a new variant of the Pummerer reaction serves as a precursor to dibromophakellstatin.

AB - (Chemical Equation Presented) The diastereoselective oxidative cyclization of a dihydrooroidin derivative is reported. The thioimidate product formed by application of a new variant of the Pummerer reaction serves as a precursor to dibromophakellstatin.

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U2 - 10.1021/ol0500113

DO - 10.1021/ol0500113

M3 - Article

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SN - 1523-7060

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EP - 931

JO - Organic Letters

JF - Organic Letters

IS - 5

ER -

Extending pummerer reaction chemistry. Synthesis of (±)- dibromophakellstatin by oxidative cyclization of an imidazole derivative

Abstract

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