Field emission properties of BN/C and BN@C hybrid nanotubes

Vincent Meunier; Marco Buongiorno Nardelli; William Shelton; Christopher Roland; Jerry Bernholc; Thomas Zacharia

doi:10.1557/proc-739-h5.7

Field emission properties of BN/C and BN@C hybrid nanotubes

Vincent Meunier, Marco Buongiorno Nardelli, William Shelton, Christopher Roland, Jerry Bernholc, Thomas Zacharia

Engineering Science and Mechanics

Research output: Contribution to journal › Conference article › peer-review

1 Scopus citations

Abstract

Our simulations predict that boron-nitride (BN) doping in carbon nanotubes can greatly improve the field emission properties of these systems. The intrinsic electric field associated with the polarity of the B-N bond enhances the emitted current density through a reduction of the work function at the tip. Using a combination of real-space and plane-wave ab initio methods, we show that this effect is present in both coaxial (BN@C) and linear (BN/C) nanotubular assemblies. While in the coaxial geometry the improvement amounts to a factor of five, the current, density is predicted to increase by up to two orders of magnitude in BN/C superlattices.

Original language	English (US)
Pages (from-to)	181-186
Number of pages	6
Journal	Materials Research Society Symposium - Proceedings
Volume	739
DOIs	https://doi.org/10.1557/proc-739-h5.7
State	Published - 2002
Event	Three-Dimensional Nanoengineered Assemblies - Boston, MA, United States Duration: Dec 1 2002 → Dec 5 2002

All Science Journal Classification (ASJC) codes

General Materials Science
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering

Access to Document

10.1557/proc-739-h5.7

Cite this

@article{4eb81b3ca6c448b0babc23c1e6bb825e,

title = "Field emission properties of BN/C and BN@C hybrid nanotubes",

abstract = "Our simulations predict that boron-nitride (BN) doping in carbon nanotubes can greatly improve the field emission properties of these systems. The intrinsic electric field associated with the polarity of the B-N bond enhances the emitted current density through a reduction of the work function at the tip. Using a combination of real-space and plane-wave ab initio methods, we show that this effect is present in both coaxial (BN@C) and linear (BN/C) nanotubular assemblies. While in the coaxial geometry the improvement amounts to a factor of five, the current, density is predicted to increase by up to two orders of magnitude in BN/C superlattices.",

author = "Vincent Meunier and Nardelli, \{Marco Buongiorno\} and William Shelton and Christopher Roland and Jerry Bernholc and Thomas Zacharia",

year = "2002",

doi = "10.1557/proc-739-h5.7",

language = "English (US)",

volume = "739",

pages = "181--186",

journal = "Materials Research Society Symposium - Proceedings",

issn = "0272-9172",

publisher = "Materials Research Society",

note = "Three-Dimensional Nanoengineered Assemblies ; Conference date: 01-12-2002 Through 05-12-2002",

}

TY - JOUR

T1 - Field emission properties of BN/C and BN@C hybrid nanotubes

AU - Meunier, Vincent

AU - Nardelli, Marco Buongiorno

AU - Shelton, William

AU - Roland, Christopher

AU - Bernholc, Jerry

AU - Zacharia, Thomas

PY - 2002

Y1 - 2002

N2 - Our simulations predict that boron-nitride (BN) doping in carbon nanotubes can greatly improve the field emission properties of these systems. The intrinsic electric field associated with the polarity of the B-N bond enhances the emitted current density through a reduction of the work function at the tip. Using a combination of real-space and plane-wave ab initio methods, we show that this effect is present in both coaxial (BN@C) and linear (BN/C) nanotubular assemblies. While in the coaxial geometry the improvement amounts to a factor of five, the current, density is predicted to increase by up to two orders of magnitude in BN/C superlattices.

AB - Our simulations predict that boron-nitride (BN) doping in carbon nanotubes can greatly improve the field emission properties of these systems. The intrinsic electric field associated with the polarity of the B-N bond enhances the emitted current density through a reduction of the work function at the tip. Using a combination of real-space and plane-wave ab initio methods, we show that this effect is present in both coaxial (BN@C) and linear (BN/C) nanotubular assemblies. While in the coaxial geometry the improvement amounts to a factor of five, the current, density is predicted to increase by up to two orders of magnitude in BN/C superlattices.

UR - https://www.scopus.com/pages/publications/0042622335

UR - https://www.scopus.com/inward/citedby.url?scp=0042622335&partnerID=8YFLogxK

U2 - 10.1557/proc-739-h5.7

DO - 10.1557/proc-739-h5.7

M3 - Conference article

AN - SCOPUS:0042622335

SN - 0272-9172

VL - 739

SP - 181

EP - 186

JO - Materials Research Society Symposium - Proceedings

JF - Materials Research Society Symposium - Proceedings

T2 - Three-Dimensional Nanoengineered Assemblies

Y2 - 1 December 2002 through 5 December 2002

ER -

Field emission properties of BN/C and BN@C hybrid nanotubes

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this