Field ionization kinetics: Phenylhexanone

Donald G. Patterson; Richard B. Scott; Peter Brown

doi:10.1002/oms.1210120611

Field ionization kinetics: Phenylhexanone

Donald G. Patterson, Richard B. Scott, Peter Brown

Forensic Science Program

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

A Varian Atlas SMIB double focusing mass spectrometer has been modified for field ionization kinetics measurements. Computer programs have been written for the calculation and display of potential maps, ion trajectories, and the transformation to ion lifetimes and phenomenological rate constants. The previously studied cyclohexene system has been used to check the accuracy of our method. The fragment ions generated by phenylhexanone after field ionization have also been examined by field ionization kinetics, including cleavage and rearrangement reactions, H/D randomization and temperature effects.

Original language	English (US)
Pages (from-to)	395-401
Number of pages	7
Journal	Organic Mass Spectrometry
Volume	12
Issue number	6
DOIs	https://doi.org/10.1002/oms.1210120611
State	Published - Jun 1977

All Science Journal Classification (ASJC) codes

Biochemistry
Molecular Medicine
Instrumentation

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10.1002/oms.1210120611

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title = "Field ionization kinetics: Phenylhexanone",

abstract = "A Varian Atlas SMIB double focusing mass spectrometer has been modified for field ionization kinetics measurements. Computer programs have been written for the calculation and display of potential maps, ion trajectories, and the transformation to ion lifetimes and phenomenological rate constants. The previously studied cyclohexene system has been used to check the accuracy of our method. The fragment ions generated by phenylhexanone after field ionization have also been examined by field ionization kinetics, including cleavage and rearrangement reactions, H/D randomization and temperature effects.",

author = "Patterson, {Donald G.} and Scott, {Richard B.} and Peter Brown",

year = "1977",

month = jun,

doi = "10.1002/oms.1210120611",

language = "English (US)",

volume = "12",

pages = "395--401",

journal = "Organic Mass Spectrometry",

issn = "0030-493X",

publisher = "Wiley-Liss Inc.",

number = "6",

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TY - JOUR

T1 - Field ionization kinetics

T2 - Phenylhexanone

AU - Patterson, Donald G.

AU - Scott, Richard B.

AU - Brown, Peter

PY - 1977/6

Y1 - 1977/6

N2 - A Varian Atlas SMIB double focusing mass spectrometer has been modified for field ionization kinetics measurements. Computer programs have been written for the calculation and display of potential maps, ion trajectories, and the transformation to ion lifetimes and phenomenological rate constants. The previously studied cyclohexene system has been used to check the accuracy of our method. The fragment ions generated by phenylhexanone after field ionization have also been examined by field ionization kinetics, including cleavage and rearrangement reactions, H/D randomization and temperature effects.

AB - A Varian Atlas SMIB double focusing mass spectrometer has been modified for field ionization kinetics measurements. Computer programs have been written for the calculation and display of potential maps, ion trajectories, and the transformation to ion lifetimes and phenomenological rate constants. The previously studied cyclohexene system has been used to check the accuracy of our method. The fragment ions generated by phenylhexanone after field ionization have also been examined by field ionization kinetics, including cleavage and rearrangement reactions, H/D randomization and temperature effects.

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U2 - 10.1002/oms.1210120611

DO - 10.1002/oms.1210120611

M3 - Article

AN - SCOPUS:84986958374

SN - 0030-493X

VL - 12

SP - 395

EP - 401

JO - Organic Mass Spectrometry

JF - Organic Mass Spectrometry

IS - 6

ER -

Field ionization kinetics: Phenylhexanone

Abstract

All Science Journal Classification (ASJC) codes

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