First Step in Catalysis of the Radical S-Adenosylmethionine Methylthiotransferase MiaB Yields an Intermediate with a [3Fe-4S]⁰-Like Auxiliary Cluster

Keyphrases

• MiaB 100%
• Methylthiotransferase 100%
• Radical S-Adenosylmethionine 100%
• Mssbauer 33%
• Adenosine 33%
• Isopentenol 33%
• Transfer RNA (tRNA) 16%
• Family Members 16%
• S-adenosylmethionine 16%
• Sulfur 16%
• Sulfur Atom 16%
• Spectroscopic Properties 16%
• Methylation 16%
• Mixed Valence 16%
• Radical Intermediates 16%
• Sulfur Source 16%
• Methylthiol 16%
• Reductive Cleavage 16%
• Coordination Sites 16%
• Fe Sites 16%
• Bacteroides thetaiotaomicron 16%

Biochemistry, Genetics and Molecular Biology

• S-Adenosyl Methionine 100%
• Enzyme 50%
• Adenosine 50%
• Anabolism 25%
• Methylation 25%
• Bacteroides Thetaiotaomicron 25%
• Transfer RNA 25%

Chemistry

• Adenosine 100%
• Sulfur Atom 50%
• Reductive Elimination Reaction 50%
• methylation 50%
• Transfer RNA 50%