Flexible free-standing graphene-TiO 2 hybrid paper for use as lithium ion battery anode materials

Tao Hu; Xiang Sun; Hongtao Sun; Mingpeng Yu; Fengyuan Lu; Changsheng Liu; Jie Lian

doi:10.1016/j.carbon.2012.08.059

Flexible free-standing graphene-TiO ₂ hybrid paper for use as lithium ion battery anode materials

Tao Hu
, Xiang Sun
, Hongtao Sun
, Mingpeng Yu
, Fengyuan Lu
, Changsheng Liu
, Jie Lian

Research output: Contribution to journal › Article › peer-review

167 Scopus citations

Abstract

Flexible and binder-free graphene-TiO ₂ paper was prepared by a simple route. A unique 3-D nano-structure was achieved with nano-sized TiO ₂ intercalated between graphene layers as pillars, significantly increasing the Li-ion insertion/extraction rate. At a current rate of 2 Ag ^-1, the specific capacity can reach 122 mAhg ^-1 after 100 charge/discharge cycles. More remarkably, the flexible graphene/TiO ₂ hybrid paper shows an excellent stability when the rates decrease from 4 Ag ^-1 back to 200 mAg ^-1 with the retained capacity of 175 mAhg ^-1.

Original language	English (US)
Pages (from-to)	322-326
Number of pages	5
Journal	Carbon
Volume	51
Issue number	1
DOIs	https://doi.org/10.1016/j.carbon.2012.08.059
State	Published - Jan 2013

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

All Science Journal Classification (ASJC) codes

General Chemistry
General Materials Science

Access to Document

10.1016/j.carbon.2012.08.059

Cite this

@article{0765e989659a47a09816805b470348fd,

title = "Flexible free-standing graphene-TiO 2 hybrid paper for use as lithium ion battery anode materials",

abstract = "Flexible and binder-free graphene-TiO 2 paper was prepared by a simple route. A unique 3-D nano-structure was achieved with nano-sized TiO 2 intercalated between graphene layers as pillars, significantly increasing the Li-ion insertion/extraction rate. At a current rate of 2 Ag -1, the specific capacity can reach 122 mAhg -1 after 100 charge/discharge cycles. More remarkably, the flexible graphene/TiO 2 hybrid paper shows an excellent stability when the rates decrease from 4 Ag -1 back to 200 mAg -1 with the retained capacity of 175 mAhg -1.",

author = "Tao Hu and Xiang Sun and Hongtao Sun and Mingpeng Yu and Fengyuan Lu and Changsheng Liu and Jie Lian",

note = "Funding Information: This work was supported by a NSF career award under the Award number of DMR 1151028. T. Hu and C. Liu also acknowledge the State Scholarship Fund of the China Scholarship Council and the Fundamental Research Funds for the Central Universities (N100702001). ",

year = "2013",

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doi = "10.1016/j.carbon.2012.08.059",

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T1 - Flexible free-standing graphene-TiO 2 hybrid paper for use as lithium ion battery anode materials

AU - Hu, Tao

AU - Sun, Xiang

AU - Sun, Hongtao

AU - Yu, Mingpeng

AU - Lu, Fengyuan

AU - Liu, Changsheng

AU - Lian, Jie

N1 - Funding Information: This work was supported by a NSF career award under the Award number of DMR 1151028. T. Hu and C. Liu also acknowledge the State Scholarship Fund of the China Scholarship Council and the Fundamental Research Funds for the Central Universities (N100702001).

PY - 2013/1

Y1 - 2013/1

N2 - Flexible and binder-free graphene-TiO 2 paper was prepared by a simple route. A unique 3-D nano-structure was achieved with nano-sized TiO 2 intercalated between graphene layers as pillars, significantly increasing the Li-ion insertion/extraction rate. At a current rate of 2 Ag -1, the specific capacity can reach 122 mAhg -1 after 100 charge/discharge cycles. More remarkably, the flexible graphene/TiO 2 hybrid paper shows an excellent stability when the rates decrease from 4 Ag -1 back to 200 mAg -1 with the retained capacity of 175 mAhg -1.

AB - Flexible and binder-free graphene-TiO 2 paper was prepared by a simple route. A unique 3-D nano-structure was achieved with nano-sized TiO 2 intercalated between graphene layers as pillars, significantly increasing the Li-ion insertion/extraction rate. At a current rate of 2 Ag -1, the specific capacity can reach 122 mAhg -1 after 100 charge/discharge cycles. More remarkably, the flexible graphene/TiO 2 hybrid paper shows an excellent stability when the rates decrease from 4 Ag -1 back to 200 mAg -1 with the retained capacity of 175 mAhg -1.

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