Functionalization of polyesters with multiple B vitamins

Andrew G. Soxman; Jenna M. DeLuca; Kylie M. Kinlough; David F. Iwig; Robert T. Mathers

doi:10.1002/pola.28713

Functionalization of polyesters with multiple B vitamins

Andrew G. Soxman
, Jenna M. DeLuca
, Kylie M. Kinlough
, David F. Iwig
, Robert T. Mathers

Penn State New Kensington

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

A method to covalently attach combinations of six different B vitamins provided an avenue to new functional thermosets without multi-step coupling reactions. The melt polymerization strategy required no organic solvent and facilitated covalent attachment of OH (B₁, B₂, B₅, B₆) or COOH (B₇, B₉) groups on B vitamins via Fischer esterification. Characterization of model reactions with LC/MS, FTIR, and GPC confirmed covalent attachment. Based on control experiments, B vitamins demonstrated unexpected thermal stability and appreciable solubility in the melt polymerization. This approach was demonstrated with citric acid and diglycerol, but has wide-ranging potential for other polar monomers with negative octanol–water partition coefficients (LogP).

Original language	English (US)
Pages (from-to)	3308-3316
Number of pages	9
Journal	Journal of Polymer Science, Part A: Polymer Chemistry
Volume	55
Issue number	19
DOIs	https://doi.org/10.1002/pola.28713
State	Published - Oct 1 2017

All Science Journal Classification (ASJC) codes

Polymers and Plastics
Organic Chemistry
Materials Chemistry

Access to Document

10.1002/pola.28713

Cite this

@article{421d134033b24d8eb5fe2fa71a620bd9,

title = "Functionalization of polyesters with multiple B vitamins",

abstract = "A method to covalently attach combinations of six different B vitamins provided an avenue to new functional thermosets without multi-step coupling reactions. The melt polymerization strategy required no organic solvent and facilitated covalent attachment of OH (B1, B2, B5, B6) or COOH (B7, B9) groups on B vitamins via Fischer esterification. Characterization of model reactions with LC/MS, FTIR, and GPC confirmed covalent attachment. Based on control experiments, B vitamins demonstrated unexpected thermal stability and appreciable solubility in the melt polymerization. This approach was demonstrated with citric acid and diglycerol, but has wide-ranging potential for other polar monomers with negative octanol–water partition coefficients (LogP).",

author = "Soxman, \{Andrew G.\} and DeLuca, \{Jenna M.\} and Kinlough, \{Kylie M.\} and Iwig, \{David F.\} and Mathers, \{Robert T.\}",

note = "Publisher Copyright: {\textcopyright} 2017 Wiley Periodicals, Inc.",

year = "2017",

month = oct,

day = "1",

doi = "10.1002/pola.28713",

language = "English (US)",

volume = "55",

pages = "3308--3316",

journal = "Journal of Polymer Science, Part A: Polymer Chemistry",

issn = "0887-624X",

publisher = "John Wiley \& Sons Inc.",

number = "19",

}

TY - JOUR

T1 - Functionalization of polyesters with multiple B vitamins

AU - Soxman, Andrew G.

AU - DeLuca, Jenna M.

AU - Kinlough, Kylie M.

AU - Iwig, David F.

AU - Mathers, Robert T.

PY - 2017/10/1

Y1 - 2017/10/1

N2 - A method to covalently attach combinations of six different B vitamins provided an avenue to new functional thermosets without multi-step coupling reactions. The melt polymerization strategy required no organic solvent and facilitated covalent attachment of OH (B1, B2, B5, B6) or COOH (B7, B9) groups on B vitamins via Fischer esterification. Characterization of model reactions with LC/MS, FTIR, and GPC confirmed covalent attachment. Based on control experiments, B vitamins demonstrated unexpected thermal stability and appreciable solubility in the melt polymerization. This approach was demonstrated with citric acid and diglycerol, but has wide-ranging potential for other polar monomers with negative octanol–water partition coefficients (LogP).

AB - A method to covalently attach combinations of six different B vitamins provided an avenue to new functional thermosets without multi-step coupling reactions. The melt polymerization strategy required no organic solvent and facilitated covalent attachment of OH (B1, B2, B5, B6) or COOH (B7, B9) groups on B vitamins via Fischer esterification. Characterization of model reactions with LC/MS, FTIR, and GPC confirmed covalent attachment. Based on control experiments, B vitamins demonstrated unexpected thermal stability and appreciable solubility in the melt polymerization. This approach was demonstrated with citric acid and diglycerol, but has wide-ranging potential for other polar monomers with negative octanol–water partition coefficients (LogP).

UR - https://www.scopus.com/pages/publications/85023773272

UR - https://www.scopus.com/pages/publications/85023773272#tab=citedBy

U2 - 10.1002/pola.28713

DO - 10.1002/pola.28713

M3 - Article

AN - SCOPUS:85023773272

SN - 0887-624X

VL - 55

SP - 3308

EP - 3316

JO - Journal of Polymer Science, Part A: Polymer Chemistry

JF - Journal of Polymer Science, Part A: Polymer Chemistry

IS - 19

ER -

Functionalization of polyesters with multiple B vitamins

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this