Glass fiber surface effects in silane coupling

C. G. Pantano; L. A. Carman; S. Warner

doi:10.1163/156856192X00043

Glass fiber surface effects in silane coupling

C. G. Pantano, L. A. Carman, S. Warner

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26 Scopus citations

Abstract

Glass fibers with the nominal E-glass composition were synthesized with 0, 2, 4, or 6% B₂O₃. The influence of the B₂O₃ content on aminosilane adsorption was evaluated using X-ray photoelectron spectroscopy (XPS) and zeta potential measurements. The water adsorption capacity of the silane-treated fibers was measured using a gravimetric technique. It was found that the presence of B₂O₃ enhanced the adsorption of aminosilane, but, more significantly, it greatly increased the water adsorption capacity of the silane-treated fibers. This effect of the B₂O₃ on water adsorption was considerably less evident in the untreated fibers. The solubility of boron and aluminum appears to play a role in determining the chemical and physical structure of the silane overlayer.

Original language	English (US)
Pages (from-to)	49-60
Number of pages	12
Journal	Journal of Adhesion Science and Technology
Volume	6
Issue number	1
DOIs	https://doi.org/10.1163/156856192X00043
State	Published - Jan 1 1992

All Science Journal Classification (ASJC) codes

Chemistry(all)
Mechanics of Materials
Surfaces and Interfaces
Surfaces, Coatings and Films
Materials Chemistry

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title = "Glass fiber surface effects in silane coupling",

abstract = "Glass fibers with the nominal E-glass composition were synthesized with 0, 2, 4, or 6% B2O3. The influence of the B2O3 content on aminosilane adsorption was evaluated using X-ray photoelectron spectroscopy (XPS) and zeta potential measurements. The water adsorption capacity of the silane-treated fibers was measured using a gravimetric technique. It was found that the presence of B2O3 enhanced the adsorption of aminosilane, but, more significantly, it greatly increased the water adsorption capacity of the silane-treated fibers. This effect of the B2O3 on water adsorption was considerably less evident in the untreated fibers. The solubility of boron and aluminum appears to play a role in determining the chemical and physical structure of the silane overlayer.",

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T1 - Glass fiber surface effects in silane coupling

AU - Pantano, C. G.

AU - Carman, L. A.

AU - Warner, S.

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N2 - Glass fibers with the nominal E-glass composition were synthesized with 0, 2, 4, or 6% B2O3. The influence of the B2O3 content on aminosilane adsorption was evaluated using X-ray photoelectron spectroscopy (XPS) and zeta potential measurements. The water adsorption capacity of the silane-treated fibers was measured using a gravimetric technique. It was found that the presence of B2O3 enhanced the adsorption of aminosilane, but, more significantly, it greatly increased the water adsorption capacity of the silane-treated fibers. This effect of the B2O3 on water adsorption was considerably less evident in the untreated fibers. The solubility of boron and aluminum appears to play a role in determining the chemical and physical structure of the silane overlayer.

AB - Glass fibers with the nominal E-glass composition were synthesized with 0, 2, 4, or 6% B2O3. The influence of the B2O3 content on aminosilane adsorption was evaluated using X-ray photoelectron spectroscopy (XPS) and zeta potential measurements. The water adsorption capacity of the silane-treated fibers was measured using a gravimetric technique. It was found that the presence of B2O3 enhanced the adsorption of aminosilane, but, more significantly, it greatly increased the water adsorption capacity of the silane-treated fibers. This effect of the B2O3 on water adsorption was considerably less evident in the untreated fibers. The solubility of boron and aluminum appears to play a role in determining the chemical and physical structure of the silane overlayer.

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Glass fiber surface effects in silane coupling

Abstract

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