Gold(I) Vinylidene Complexes as Reactive Intermediates and Their Tendency to π-Backbond

Laura Nunes Dos Santos Comprido; Johannes E.M.N. Klein; Gerald Knizia; Johannes Kästner; A. Stephen K. Hashmi

doi:10.1002/chem.201504511

Gold(I) Vinylidene Complexes as Reactive Intermediates and Their Tendency to π-Backbond

Laura Nunes Dos Santos Comprido
, Johannes E.M.N. Klein
, Gerald Knizia
, Johannes Kästner
, A. Stephen K. Hashmi

Chemistry

Research output: Contribution to journal › Article › peer-review

67 Scopus citations

Abstract

We herein report a computational study of the bonding in gold(I) vinylidene complexes and compare them to their carbene and CO analogues. The relevance of these intermediates is analysed for the intramolecular cyclisation leading to vinyl sulfonates.

Original language	English (US)
Pages (from-to)	2892-2895
Number of pages	4
Journal	Chemistry - A European Journal
Volume	22
Issue number	9
DOIs	https://doi.org/10.1002/chem.201504511
State	Published - Feb 24 2016

All Science Journal Classification (ASJC) codes

Catalysis
General Chemistry
Organic Chemistry

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10.1002/chem.201504511

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title = "Gold(I) Vinylidene Complexes as Reactive Intermediates and Their Tendency to π-Backbond",

abstract = "We herein report a computational study of the bonding in gold(I) vinylidene complexes and compare them to their carbene and CO analogues. The relevance of these intermediates is analysed for the intramolecular cyclisation leading to vinyl sulfonates.",

author = "\{Nunes Dos Santos Comprido\}, Laura and Klein, \{Johannes E.M.N.\} and Gerald Knizia and Johannes K{\"a}stner and Hashmi, \{A. Stephen K.\}",

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AU - Nunes Dos Santos Comprido, Laura

AU - Klein, Johannes E.M.N.

AU - Knizia, Gerald

AU - Kästner, Johannes

AU - Hashmi, A. Stephen K.

PY - 2016/2/24

Y1 - 2016/2/24

N2 - We herein report a computational study of the bonding in gold(I) vinylidene complexes and compare them to their carbene and CO analogues. The relevance of these intermediates is analysed for the intramolecular cyclisation leading to vinyl sulfonates.

AB - We herein report a computational study of the bonding in gold(I) vinylidene complexes and compare them to their carbene and CO analogues. The relevance of these intermediates is analysed for the intramolecular cyclisation leading to vinyl sulfonates.

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U2 - 10.1002/chem.201504511

DO - 10.1002/chem.201504511

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JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

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Gold(I) Vinylidene Complexes as Reactive Intermediates and Their Tendency to π-Backbond

Abstract

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