TY - JOUR
T1 - Ground- and excited-state spectral and redox properties of cadmium(II) texaphyrin
AU - Maiya, Bhaskar G.
AU - Harriman, Anthony
AU - Sessler, Jonathan L.
AU - Hemmi, Gregory
AU - Murai, Toshiaki
AU - Mallouk, Thomas E.
PY - 1989
Y1 - 1989
N2 - Cadmium texaphyrin, [(TXP)Cd]+, a representative of a new family of expanded porphyrins, has an absorption maximum around 760 nm in acetonitrile solution. The first excited triplet state, which is formed with a quantum yield of 0.9, is quenched by O2, via an energy-transfer process, and by aromatic amines, via an electron-transfer reaction. This latter process produces [(TXP)Cd]0, the neutral radical, as characterized by flash photolysis methods, with an overall quantum efficiency of about 60%. The potential of the texaphyrin family as photosensitizers for photodynamic therapy is highlighted.
AB - Cadmium texaphyrin, [(TXP)Cd]+, a representative of a new family of expanded porphyrins, has an absorption maximum around 760 nm in acetonitrile solution. The first excited triplet state, which is formed with a quantum yield of 0.9, is quenched by O2, via an energy-transfer process, and by aromatic amines, via an electron-transfer reaction. This latter process produces [(TXP)Cd]0, the neutral radical, as characterized by flash photolysis methods, with an overall quantum efficiency of about 60%. The potential of the texaphyrin family as photosensitizers for photodynamic therapy is highlighted.
UR - https://www.scopus.com/pages/publications/0001047021
UR - https://www.scopus.com/pages/publications/0001047021#tab=citedBy
U2 - 10.1021/j100361a027
DO - 10.1021/j100361a027
M3 - Article
AN - SCOPUS:0001047021
SN - 0022-3654
VL - 93
SP - 8111
EP - 8115
JO - Journal of physical chemistry
JF - Journal of physical chemistry
IS - 24
ER -