TY - JOUR
T1 - Hexa-1,5-diyn-3-ol ethers as tetramethynyl synthons in cobalt-catalysed acetylene co-oligomerisations; a one-step synthesis of 2,3,6,7- tetrakistrimethylsilylnaphthalene
AU - Funk, Raymond L.
AU - Vollhardt, K. Peter C.
N1 - Funding Information:
Cp = cyclopentadienyl, py = pyridine. o-xylylenes from readily available precursors suggests that by appropriate choice of starting acetylenes considerable improvement of currently existing synthetic methods involving benzocyclobutenes2 should be possible. We thank the California Division of the American Cancer Society, the National Institute of Health, the National Science Foundation, and the A.P. Sloan Founda- tion for financial support.
PY - 1976
Y1 - 1976
N2 - Reaction of hexa-1,5-diyn-3-ol ether derivatives with bistrimethylsilylacetylene in the presence of catalytic amounts of [CpCo(CO)2] (Cp = cyclopentadienyl) gives 2,3,6,7- tetrakistrimethylsily Inaphthalene.
AB - Reaction of hexa-1,5-diyn-3-ol ether derivatives with bistrimethylsilylacetylene in the presence of catalytic amounts of [CpCo(CO)2] (Cp = cyclopentadienyl) gives 2,3,6,7- tetrakistrimethylsily Inaphthalene.
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U2 - 10.1039/C39760000833
DO - 10.1039/C39760000833
M3 - Article
AN - SCOPUS:37049102875
SN - 0022-4936
SP - 833
EP - 834
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 20
ER -