Hexadecane autoxidation. Product analysis and reaction pathways

S. Blaine; P. E. Savage

Hexadecane autoxidation. Product analysis and reaction pathways

S. Blaine
, P. E. Savage

Chemical Engineering

Research output: Contribution to journal › Conference article › peer-review

3 Scopus citations

Abstract

This paper presents an approach for resolving and modeling liquid-phase autoxidation pathways. The approach requires quantitative determination of oxygen-containing functional group concentrations, and this is presently accomplished by a novel combination of titrimetric and spectroscopic methods. The results from initial autoxidation experiments using n-hexadecane proved to be qualitatively consistent with a global reaction pathway model assembled from the literature.

Original language	English (US)
Pages (from-to)	239-244
Number of pages	6
Journal	American Chemical Society, Division of Petroleum Chemistry, Preprints
Volume	35
Issue number	2
State	Published - Apr 1990
Event	Symposium on Selective Catalytic Oxidation of Hydrocarbons - Presented before the Division of Petroleum Chemistry, ACS, Boston Meeting - Boston, MA, USA Duration: Apr 22 1990 → Apr 27 1990

All Science Journal Classification (ASJC) codes

Fuel Technology

Cite this

@article{a8b5b14c23a54ce0ad1e3106f1644b9f,

title = "Hexadecane autoxidation. Product analysis and reaction pathways",

abstract = "This paper presents an approach for resolving and modeling liquid-phase autoxidation pathways. The approach requires quantitative determination of oxygen-containing functional group concentrations, and this is presently accomplished by a novel combination of titrimetric and spectroscopic methods. The results from initial autoxidation experiments using n-hexadecane proved to be qualitatively consistent with a global reaction pathway model assembled from the literature.",

author = "S. Blaine and Savage, \{P. E.\}",

year = "1990",

month = apr,

language = "English (US)",

volume = "35",

pages = "239--244",

journal = "American Chemical Society, Division of Petroleum Chemistry, Preprints",

issn = "0569-3799",

publisher = "American Chemical Society",

number = "2",

note = "Symposium on Selective Catalytic Oxidation of Hydrocarbons - Presented before the Division of Petroleum Chemistry, ACS, Boston Meeting ; Conference date: 22-04-1990 Through 27-04-1990",

}

TY - JOUR

T1 - Hexadecane autoxidation. Product analysis and reaction pathways

AU - Blaine, S.

AU - Savage, P. E.

PY - 1990/4

Y1 - 1990/4

N2 - This paper presents an approach for resolving and modeling liquid-phase autoxidation pathways. The approach requires quantitative determination of oxygen-containing functional group concentrations, and this is presently accomplished by a novel combination of titrimetric and spectroscopic methods. The results from initial autoxidation experiments using n-hexadecane proved to be qualitatively consistent with a global reaction pathway model assembled from the literature.

AB - This paper presents an approach for resolving and modeling liquid-phase autoxidation pathways. The approach requires quantitative determination of oxygen-containing functional group concentrations, and this is presently accomplished by a novel combination of titrimetric and spectroscopic methods. The results from initial autoxidation experiments using n-hexadecane proved to be qualitatively consistent with a global reaction pathway model assembled from the literature.

UR - https://www.scopus.com/pages/publications/0025408943

UR - https://www.scopus.com/pages/publications/0025408943#tab=citedBy

M3 - Conference article

AN - SCOPUS:0025408943

SN - 0569-3799

VL - 35

SP - 239

EP - 244

JO - American Chemical Society, Division of Petroleum Chemistry, Preprints

JF - American Chemical Society, Division of Petroleum Chemistry, Preprints

IS - 2

T2 - Symposium on Selective Catalytic Oxidation of Hydrocarbons - Presented before the Division of Petroleum Chemistry, ACS, Boston Meeting

Y2 - 22 April 1990 through 27 April 1990

ER -

Hexadecane autoxidation. Product analysis and reaction pathways

Abstract

All Science Journal Classification (ASJC) codes

Other files and links

Fingerprint

Cite this