High-Pressure Synthesis of an Alkali Metal-Transition Metal Laves Phase: KAg2

M. Hasegawa; T. Atou; J. V. Badding

doi:10.1006/jssc.1997.7391

High-Pressure Synthesis of an Alkali Metal-Transition Metal Laves Phase: KAg₂

M. Hasegawa
, T. Atou
, J. V. Badding

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

A new C14 Laves phase was synthesized by direct reaction of potassium and silver at high pressure in a diamond anvil cell. The structure was refined by Rietveld analysis on powder diffraction data in the space groupP6₃/mmcto anR_F2value of 0.034. The lattice parameters area=5.589(5) andc=9.476(1). Formation of this phase under pressure is in agreement with predictions based on Miedema's rules. A novel double-sided laser heating system was developed for the synthesis of KAg₂.

Original language	English (US)
Pages (from-to)	311-315
Number of pages	5
Journal	Journal of Solid State Chemistry
Volume	130
Issue number	2
DOIs	https://doi.org/10.1006/jssc.1997.7391
State	Published - May 1997

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Ceramics and Composites
Condensed Matter Physics
Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1006/jssc.1997.7391

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title = "High-Pressure Synthesis of an Alkali Metal-Transition Metal Laves Phase: KAg2",

abstract = "A new C14 Laves phase was synthesized by direct reaction of potassium and silver at high pressure in a diamond anvil cell. The structure was refined by Rietveld analysis on powder diffraction data in the space groupP63/mmcto anRF2value of 0.034. The lattice parameters area=5.589(5) andc=9.476(1). Formation of this phase under pressure is in agreement with predictions based on Miedema's rules. A novel double-sided laser heating system was developed for the synthesis of KAg2.",

author = "M. Hasegawa and T. Atou and Badding, \{J. V.\}",

note = "Funding Information: This work was supported by a National Science Foundation Young Investigator Award, the donors of the Petroleum Research Fund (administered by the American Chemical Society), and a David and Lucile Packard Foundation Fellowship. We thank John Parise for valuable discussions about Rietveld analysis.",

year = "1997",

month = may,

doi = "10.1006/jssc.1997.7391",

language = "English (US)",

volume = "130",

pages = "311--315",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Academic Press Inc.",

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TY - JOUR

T1 - High-Pressure Synthesis of an Alkali Metal-Transition Metal Laves Phase

T2 - KAg2

AU - Hasegawa, M.

AU - Atou, T.

AU - Badding, J. V.

N1 - Funding Information: This work was supported by a National Science Foundation Young Investigator Award, the donors of the Petroleum Research Fund (administered by the American Chemical Society), and a David and Lucile Packard Foundation Fellowship. We thank John Parise for valuable discussions about Rietveld analysis.

PY - 1997/5

Y1 - 1997/5

N2 - A new C14 Laves phase was synthesized by direct reaction of potassium and silver at high pressure in a diamond anvil cell. The structure was refined by Rietveld analysis on powder diffraction data in the space groupP63/mmcto anRF2value of 0.034. The lattice parameters area=5.589(5) andc=9.476(1). Formation of this phase under pressure is in agreement with predictions based on Miedema's rules. A novel double-sided laser heating system was developed for the synthesis of KAg2.

AB - A new C14 Laves phase was synthesized by direct reaction of potassium and silver at high pressure in a diamond anvil cell. The structure was refined by Rietveld analysis on powder diffraction data in the space groupP63/mmcto anRF2value of 0.034. The lattice parameters area=5.589(5) andc=9.476(1). Formation of this phase under pressure is in agreement with predictions based on Miedema's rules. A novel double-sided laser heating system was developed for the synthesis of KAg2.

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EP - 315

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

IS - 2

ER -

High-Pressure Synthesis of an Alkali Metal-Transition Metal Laves Phase: KAg₂

Abstract

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