High resolution spectroscopy and channel-coupling treatment of the A1Σ+-b3∏ complex of NaRb

M. Tamanis; R. Ferber; A. Zaitsevskii; E. A. Pazyuk; A. V. Stolyarov; Hongmin Chen; Jianbing Qi; Henry Wang; William C. Stwalley

doi:10.1063/1.1505442

High resolution spectroscopy and channel-coupling treatment of the A¹Σ⁺-b³∏ complex of NaRb

M. Tamanis
, R. Ferber
, A. Zaitsevskii
, E. A. Pazyuk
, A. V. Stolyarov
, Hongmin Chen
, Jianbing Qi
, Henry Wang
, William C. Stwalley

Division of Science (Berks)

Research output: Contribution to journal › Article › peer-review

46 Scopus citations

Abstract

The fully mixed complex of the NaRb molecule based on high-resolution sub-Doppler spectroscopy and intensity measurements was studied. A two-laser V-type pump-probe excitation scheme was used to obtain A←X transition frequencies to 16 A-state vibrational levels from v=6 to v=21 with J from 8 to 23. It was shown that the inverted channel-coupling approach was useful in deperturbation analysis of strongly coupled electronic states.

Original language	English (US)
Pages (from-to)	7980-7988
Number of pages	9
Journal	Journal of Chemical Physics
Volume	117
Issue number	17
DOIs	https://doi.org/10.1063/1.1505442
State	Published - Nov 1 2002

All Science Journal Classification (ASJC) codes

General Physics and Astronomy
Physical and Theoretical Chemistry

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10.1063/1.1505442

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title = "High resolution spectroscopy and channel-coupling treatment of the A1Σ+-b3∏ complex of NaRb",

abstract = "The fully mixed complex of the NaRb molecule based on high-resolution sub-Doppler spectroscopy and intensity measurements was studied. A two-laser V-type pump-probe excitation scheme was used to obtain A←X transition frequencies to 16 A-state vibrational levels from v=6 to v=21 with J from 8 to 23. It was shown that the inverted channel-coupling approach was useful in deperturbation analysis of strongly coupled electronic states.",

author = "M. Tamanis and R. Ferber and A. Zaitsevskii and Pazyuk, \{E. A.\} and Stolyarov, \{A. V.\} and Hongmin Chen and Jianbing Qi and Henry Wang and Stwalley, \{William C.\}",

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doi = "10.1063/1.1505442",

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T1 - High resolution spectroscopy and channel-coupling treatment of the A1Σ+-b3∏ complex of NaRb

AU - Tamanis, M.

AU - Ferber, R.

AU - Zaitsevskii, A.

AU - Pazyuk, E. A.

AU - Stolyarov, A. V.

AU - Chen, Hongmin

AU - Qi, Jianbing

AU - Wang, Henry

AU - Stwalley, William C.

PY - 2002/11/1

Y1 - 2002/11/1

N2 - The fully mixed complex of the NaRb molecule based on high-resolution sub-Doppler spectroscopy and intensity measurements was studied. A two-laser V-type pump-probe excitation scheme was used to obtain A←X transition frequencies to 16 A-state vibrational levels from v=6 to v=21 with J from 8 to 23. It was shown that the inverted channel-coupling approach was useful in deperturbation analysis of strongly coupled electronic states.

AB - The fully mixed complex of the NaRb molecule based on high-resolution sub-Doppler spectroscopy and intensity measurements was studied. A two-laser V-type pump-probe excitation scheme was used to obtain A←X transition frequencies to 16 A-state vibrational levels from v=6 to v=21 with J from 8 to 23. It was shown that the inverted channel-coupling approach was useful in deperturbation analysis of strongly coupled electronic states.

UR - https://www.scopus.com/pages/publications/0036848844

UR - https://www.scopus.com/pages/publications/0036848844#tab=citedBy

U2 - 10.1063/1.1505442

DO - 10.1063/1.1505442

M3 - Article

AN - SCOPUS:0036848844

SN - 0021-9606

VL - 117

SP - 7980

EP - 7988

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 17

ER -

High resolution spectroscopy and channel-coupling treatment of the A¹Σ⁺-b³∏ complex of NaRb

Abstract

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