Highly dispersed framework zirconium phosphates -acid catalysts for pentane and hexane isomerization

S. N. Pavlova; V. A. Sadykov; G. V. Zabolotnaya; D. I. Kochubey; R. I. Maximovskaya; V. I. Zaikovskii; V. V. Kriventsov; S. V. Tsybulya; E. B. Burgina; A. M. Volodin; N. M. Ostrovskii; A. V. Simakov; T. A. Nikoro; V. B. Fenelonov; M. V. Chaikina; N. N. Kuznetsova; V. V. Lunin; D. Agrawal; R. Roy

doi:10.1016/S0167-2991(00)80828-9

Highly dispersed framework zirconium phosphates -acid catalysts for pentane and hexane isomerization

S. N. Pavlova, V. A. Sadykov, G. V. Zabolotnaya, D. I. Kochubey, R. I. Maximovskaya, V. I. Zaikovskii, V. V. Kriventsov, S. V. Tsybulya, E. B. Burgina, A. M. Volodin, N. M. Ostrovskii, A. V. Simakov, T. A. Nikoro, V. B. Fenelonov, M. V. Chaikina, N. N. Kuznetsova, V. V. Lunin, D. Agrawal, R. Roy

Materials Research Institute (MRI)

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The structural features, texture and surface properties of highly dispersed partially substituted framework zirconium phosphates synthesized via sol-gel or mechanochemical activation route followed by the hydrothermal treatment in the presence of polyethylene oxide were studied and compared with catalytic properties in the pentane and hexane isomerization. The most efficient promoter was found to be Si which increases the surface density of the Broensted Zr-OH centers. Pt-supported Si-modified systems demonstrate promising activity and selectivity in propane and hexane hydroisomerization at 300-400 °C.

Original language	English (US)
Pages (from-to)	2399-2404
Number of pages	6
Journal	Studies in Surface Science and Catalysis
Volume	130 C
DOIs	https://doi.org/10.1016/S0167-2991(00)80828-9
State	Published - 2000

All Science Journal Classification (ASJC) codes

Catalysis
Condensed Matter Physics
Physical and Theoretical Chemistry
Surfaces, Coatings and Films
Materials Chemistry

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10.1016/S0167-2991(00)80828-9

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Pavlova, S. N., Sadykov, V. A., Zabolotnaya, G. V., Kochubey, D. I., Maximovskaya, R. I., Zaikovskii, V. I., Kriventsov, V. V., Tsybulya, S. V., Burgina, E. B., Volodin, A. M., Ostrovskii, N. M., Simakov, A. V., Nikoro, T. A., Fenelonov, V. B., Chaikina, M. V., Kuznetsova, N. N., Lunin, V. V., Agrawal, D., & Roy, R. (2000). Highly dispersed framework zirconium phosphates -acid catalysts for pentane and hexane isomerization. Studies in Surface Science and Catalysis, 130 C, 2399-2404. https://doi.org/10.1016/S0167-2991(00)80828-9

@article{b3818de49e8a4277b517e477c425c1a5,

title = "Highly dispersed framework zirconium phosphates -acid catalysts for pentane and hexane isomerization",

abstract = "The structural features, texture and surface properties of highly dispersed partially substituted framework zirconium phosphates synthesized via sol-gel or mechanochemical activation route followed by the hydrothermal treatment in the presence of polyethylene oxide were studied and compared with catalytic properties in the pentane and hexane isomerization. The most efficient promoter was found to be Si which increases the surface density of the Broensted Zr-OH centers. Pt-supported Si-modified systems demonstrate promising activity and selectivity in propane and hexane hydroisomerization at 300-400 °C.",

author = "Pavlova, {S. N.} and Sadykov, {V. A.} and Zabolotnaya, {G. V.} and Kochubey, {D. I.} and Maximovskaya, {R. I.} and Zaikovskii, {V. I.} and Kriventsov, {V. V.} and Tsybulya, {S. V.} and Burgina, {E. B.} and Volodin, {A. M.} and Ostrovskii, {N. M.} and Simakov, {A. V.} and Nikoro, {T. A.} and Fenelonov, {V. B.} and Chaikina, {M. V.} and Kuznetsova, {N. N.} and Lunin, {V. V.} and D. Agrawal and R. Roy",

year = "2000",

doi = "10.1016/S0167-2991(00)80828-9",

language = "English (US)",

volume = "130 C",

pages = "2399--2404",

journal = "Studies in Surface Science and Catalysis",

issn = "0167-2991",

publisher = "Elsevier Inc.",

}

Pavlova, SN, Sadykov, VA, Zabolotnaya, GV, Kochubey, DI, Maximovskaya, RI, Zaikovskii, VI, Kriventsov, VV, Tsybulya, SV, Burgina, EB, Volodin, AM, Ostrovskii, NM, Simakov, AV, Nikoro, TA, Fenelonov, VB, Chaikina, MV, Kuznetsova, NN, Lunin, VV, Agrawal, D & Roy, R 2000, 'Highly dispersed framework zirconium phosphates -acid catalysts for pentane and hexane isomerization', Studies in Surface Science and Catalysis, vol. 130 C, pp. 2399-2404. https://doi.org/10.1016/S0167-2991(00)80828-9

TY - JOUR

T1 - Highly dispersed framework zirconium phosphates -acid catalysts for pentane and hexane isomerization

AU - Pavlova, S. N.

AU - Sadykov, V. A.

AU - Zabolotnaya, G. V.

AU - Kochubey, D. I.

AU - Maximovskaya, R. I.

AU - Zaikovskii, V. I.

AU - Kriventsov, V. V.

AU - Tsybulya, S. V.

AU - Burgina, E. B.

AU - Volodin, A. M.

AU - Ostrovskii, N. M.

AU - Simakov, A. V.

AU - Nikoro, T. A.

AU - Fenelonov, V. B.

AU - Chaikina, M. V.

AU - Kuznetsova, N. N.

AU - Lunin, V. V.

AU - Agrawal, D.

AU - Roy, R.

PY - 2000

Y1 - 2000

N2 - The structural features, texture and surface properties of highly dispersed partially substituted framework zirconium phosphates synthesized via sol-gel or mechanochemical activation route followed by the hydrothermal treatment in the presence of polyethylene oxide were studied and compared with catalytic properties in the pentane and hexane isomerization. The most efficient promoter was found to be Si which increases the surface density of the Broensted Zr-OH centers. Pt-supported Si-modified systems demonstrate promising activity and selectivity in propane and hexane hydroisomerization at 300-400 °C.

AB - The structural features, texture and surface properties of highly dispersed partially substituted framework zirconium phosphates synthesized via sol-gel or mechanochemical activation route followed by the hydrothermal treatment in the presence of polyethylene oxide were studied and compared with catalytic properties in the pentane and hexane isomerization. The most efficient promoter was found to be Si which increases the surface density of the Broensted Zr-OH centers. Pt-supported Si-modified systems demonstrate promising activity and selectivity in propane and hexane hydroisomerization at 300-400 °C.

UR - http://www.scopus.com/inward/record.url?scp=0034350802&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0034350802&partnerID=8YFLogxK

U2 - 10.1016/S0167-2991(00)80828-9

DO - 10.1016/S0167-2991(00)80828-9

M3 - Article

AN - SCOPUS:0034350802

SN - 0167-2991

VL - 130 C

SP - 2399

EP - 2404

JO - Studies in Surface Science and Catalysis

JF - Studies in Surface Science and Catalysis

ER -

Highly dispersed framework zirconium phosphates -acid catalysts for pentane and hexane isomerization

Abstract

All Science Journal Classification (ASJC) codes

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