Hybrid Polyphosphazene-Organosilicon Polymers as Useful Elastomers

Cuiyan Tong; Sawyer McCarthy; Zhongjing Li; Jinshan Guo; Qiyao Li; Carlos N. Pacheco; Yi Ren; Harry R. Allcock

doi:10.1021/acsapm.9b00381

Hybrid Polyphosphazene-Organosilicon Polymers as Useful Elastomers

Cuiyan Tong, Sawyer McCarthy, Zhongjing Li, Jinshan Guo, Qiyao Li, Carlos N. Pacheco, Yi Ren, Harry R. Allcock

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

Six high molecular weight, soluble, and stable elastomers were prepared derived from -O(CH2)3Si(CH3)3/-OCH2CF3 cosubstituted polyphosphazenes with 1-92 mol % of the organosilicon component. The surface and morphological properties are appropriate for biomaterials, soft contact printing, or other elastomeric applications. Full substitution by either side group yields thermoplastics. The syntheses were facilitated by small molecule model reactions to establish appropriate reaction conditions.

Original language	English (US)
Pages (from-to)	1881-1886
Number of pages	6
Journal	ACS Applied Polymer Materials
Volume	1
Issue number	7
DOIs	https://doi.org/10.1021/acsapm.9b00381
State	Published - Jul 12 2019

All Science Journal Classification (ASJC) codes

Process Chemistry and Technology
Polymers and Plastics
Organic Chemistry

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10.1021/acsapm.9b00381

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abstract = "Six high molecular weight, soluble, and stable elastomers were prepared derived from -O(CH2)3Si(CH3)3/-OCH2CF3 cosubstituted polyphosphazenes with 1-92 mol % of the organosilicon component. The surface and morphological properties are appropriate for biomaterials, soft contact printing, or other elastomeric applications. Full substitution by either side group yields thermoplastics. The syntheses were facilitated by small molecule model reactions to establish appropriate reaction conditions.",

author = "Cuiyan Tong and Sawyer McCarthy and Zhongjing Li and Jinshan Guo and Qiyao Li and Pacheco, {Carlos N.} and Yi Ren and Allcock, {Harry R.}",

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AU - Tong, Cuiyan

AU - McCarthy, Sawyer

AU - Li, Zhongjing

AU - Guo, Jinshan

AU - Li, Qiyao

AU - Pacheco, Carlos N.

AU - Ren, Yi

AU - Allcock, Harry R.

PY - 2019/7/12

Y1 - 2019/7/12

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AB - Six high molecular weight, soluble, and stable elastomers were prepared derived from -O(CH2)3Si(CH3)3/-OCH2CF3 cosubstituted polyphosphazenes with 1-92 mol % of the organosilicon component. The surface and morphological properties are appropriate for biomaterials, soft contact printing, or other elastomeric applications. Full substitution by either side group yields thermoplastics. The syntheses were facilitated by small molecule model reactions to establish appropriate reaction conditions.

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Hybrid Polyphosphazene-Organosilicon Polymers as Useful Elastomers

Abstract

All Science Journal Classification (ASJC) codes

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