Hybrid redox polyether melts based on polyether-tailed counterions

Enders Dickinson V; Mary Elizabeth Williams; Susan M. Hendrickson; Hitoshi Masui; Royce W. Murray

doi:10.1021/ja983184e

Hybrid redox polyether melts based on polyether-tailed counterions

Enders Dickinson V, Mary Elizabeth Williams, Susan M. Hendrickson, Hitoshi Masui, Royce W. Murray

Research output: Contribution to journal › Article › peer-review

155 Scopus citations

Abstract

Interesting ionic materials can be transformed into room temperature molten salts by combining them with polyether-tailed counterions such as polyether-tailed 2-sulfobenzoate (MePEG-BzSO₃^-) and polyether-tailed triethylammonium (MePEG-Et₃N⁺). Melts containing ruthenium hexamine, metal trisbipyridines, metal trisphenanthrolines, and ionic forms of aluminum quinolate, anthraquinone, phthalocyanine, and porphyrins are described. These melts exhibit ionic conductivities in the 7 x 10^-5 to 7 x 10^-10 Ω^-1 cm^-1 range, which permit microelectrode voltammetry in the undiluted materials, examples of which are presented.

Original language	English (US)
Pages (from-to)	613-616
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	121
Issue number	4
DOIs	https://doi.org/10.1021/ja983184e
State	Published - Feb 3 1999

All Science Journal Classification (ASJC) codes

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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title = "Hybrid redox polyether melts based on polyether-tailed counterions",

abstract = "Interesting ionic materials can be transformed into room temperature molten salts by combining them with polyether-tailed counterions such as polyether-tailed 2-sulfobenzoate (MePEG-BzSO3-) and polyether-tailed triethylammonium (MePEG-Et3N+). Melts containing ruthenium hexamine, metal trisbipyridines, metal trisphenanthrolines, and ionic forms of aluminum quinolate, anthraquinone, phthalocyanine, and porphyrins are described. These melts exhibit ionic conductivities in the 7 x 10-5 to 7 x 10-10 Ω-1 cm-1 range, which permit microelectrode voltammetry in the undiluted materials, examples of which are presented.",

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T1 - Hybrid redox polyether melts based on polyether-tailed counterions

AU - Dickinson V, Enders

AU - Williams, Mary Elizabeth

AU - Hendrickson, Susan M.

AU - Masui, Hitoshi

AU - Murray, Royce W.

PY - 1999/2/3

Y1 - 1999/2/3

N2 - Interesting ionic materials can be transformed into room temperature molten salts by combining them with polyether-tailed counterions such as polyether-tailed 2-sulfobenzoate (MePEG-BzSO3-) and polyether-tailed triethylammonium (MePEG-Et3N+). Melts containing ruthenium hexamine, metal trisbipyridines, metal trisphenanthrolines, and ionic forms of aluminum quinolate, anthraquinone, phthalocyanine, and porphyrins are described. These melts exhibit ionic conductivities in the 7 x 10-5 to 7 x 10-10 Ω-1 cm-1 range, which permit microelectrode voltammetry in the undiluted materials, examples of which are presented.

AB - Interesting ionic materials can be transformed into room temperature molten salts by combining them with polyether-tailed counterions such as polyether-tailed 2-sulfobenzoate (MePEG-BzSO3-) and polyether-tailed triethylammonium (MePEG-Et3N+). Melts containing ruthenium hexamine, metal trisbipyridines, metal trisphenanthrolines, and ionic forms of aluminum quinolate, anthraquinone, phthalocyanine, and porphyrins are described. These melts exhibit ionic conductivities in the 7 x 10-5 to 7 x 10-10 Ω-1 cm-1 range, which permit microelectrode voltammetry in the undiluted materials, examples of which are presented.

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Hybrid redox polyether melts based on polyether-tailed counterions

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