TY - JOUR
T1 - Hybrid supercapacitor materials from poly(3,4-ethylenedioxythiophene) conformally coated aligned carbon nanotubes
AU - Ghaffari, Mehdi
AU - Kosolwattana, Suppanat
AU - Zhou, Yue
AU - Lachman, Noa
AU - Lin, Minren
AU - Bhattacharya, Dhiman
AU - Gleason, Karen K.
AU - Wardle, Brian L.
AU - Zhang, Q. M.
N1 - Funding Information:
This work was supported by AFOSR under Grant No. FA9550-11-1-0192 and NSF under grant number CMMI-1130437 .
PY - 2013
Y1 - 2013
N2 - Conducting polymer poly(3,4-ethylenedioxythiophene) (PEDOT) conformally coated aligned carbon nanotubes (PEDOT/A-CNTs) were developed and investigated as the active material for supercapacitor electrode applications and the results were compared to those of non-coated CNTs as well as that of PEDOT coated randomly packed CNTs. The electrochemical performance of the electrodes was evaluated by cyclic voltammetry (CV), galvanostatic charge/discharge, and electrochemical impedance spectroscopy (EIS). The results revealed that the PEDOT conformally coated and densified (5% volume fraction, Vf) A-CNTs exhibit a specific volumetric capacitance of 84.0 F/cm3, much higher compared to the non-coated and non-densified A-CNTs (1% Vf) that had a specific capacitance of only 3.9 F/cm3. Ion insertion/de-insertion processes in the PEODT coating layers are observed in impedance spectra for the PEDOT-coated A-CNT electrodes at rates that are not limiting to cell performance relative to ion transport through the channels formed by the PEDOT/A-CNTs. Specific energy and power densities of 11.8 Wh/l and 34.0 kW/l, respectively, were obtained for these nano-tailored electrodes, with high capacitance retention compared with those of PEDOT coated random CNTs.
AB - Conducting polymer poly(3,4-ethylenedioxythiophene) (PEDOT) conformally coated aligned carbon nanotubes (PEDOT/A-CNTs) were developed and investigated as the active material for supercapacitor electrode applications and the results were compared to those of non-coated CNTs as well as that of PEDOT coated randomly packed CNTs. The electrochemical performance of the electrodes was evaluated by cyclic voltammetry (CV), galvanostatic charge/discharge, and electrochemical impedance spectroscopy (EIS). The results revealed that the PEDOT conformally coated and densified (5% volume fraction, Vf) A-CNTs exhibit a specific volumetric capacitance of 84.0 F/cm3, much higher compared to the non-coated and non-densified A-CNTs (1% Vf) that had a specific capacitance of only 3.9 F/cm3. Ion insertion/de-insertion processes in the PEODT coating layers are observed in impedance spectra for the PEDOT-coated A-CNT electrodes at rates that are not limiting to cell performance relative to ion transport through the channels formed by the PEDOT/A-CNTs. Specific energy and power densities of 11.8 Wh/l and 34.0 kW/l, respectively, were obtained for these nano-tailored electrodes, with high capacitance retention compared with those of PEDOT coated random CNTs.
UR - http://www.scopus.com/inward/record.url?scp=84884968013&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84884968013&partnerID=8YFLogxK
U2 - 10.1016/j.electacta.2013.08.191
DO - 10.1016/j.electacta.2013.08.191
M3 - Article
AN - SCOPUS:84884968013
SN - 0013-4686
VL - 112
SP - 522
EP - 528
JO - Electrochimica Acta
JF - Electrochimica Acta
ER -