Hydrogen and water intercalation into YBa2Cu3O7-δ: Structural properties of H2YBa2Cu3O8-δ

W. Günthe; R. Schöllhorn; M. Epple; H. Siegle; Ch H. Thomsen; B. Kabius; U. Poppe; J. Schubert; W. Zander

doi:10.1080/01418619908210309

Hydrogen and water intercalation into YBa₂Cu₃O₇-_δ: Structural properties of H₂YBa₂Cu₃O_8-δ

W. Günthe, R. Schöllhorn, M. Epple, H. Siegle, Ch H. Thomsen, B. Kabius, U. Poppe, J. Schubert, W. Zander

Materials Research Institute (MRI)

Research output: Contribution to journal › Article › peer-review

27 Scopus citations

Abstract

Structural properties of hydrogen- and water-intercalated superconductors YBa₂Cu₃O_7-δare discussed on the basis of new high-resolution electron microscopy, electron diffraction, X-ray diffraction, extended X-ray absorption fine structure (EXAFS) and Raman measurements. The multistep intercalation reaction proceeding at temperatures below 200°C leads to significant changes in the crystal structure via shear transformation resulting in a highly crystalline end phase. A new structure model was proposed for YBa₂Cu₃O_8-δwhich includes Cu-O single chains as in YBa₂Cu₃O_7-δThis result differs in principle from all models proposed before.

Original language	English (US)
Pages (from-to)	449-466
Number of pages	18
Journal	Philosophical Magazine A: Physics of Condensed Matter, Structure, Defects and Mechanical Properties
Volume	79
Issue number	2
DOIs	https://doi.org/10.1080/01418619908210309
State	Published - Feb 1999

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
General Materials Science
Condensed Matter Physics
Physics and Astronomy (miscellaneous)
Metals and Alloys

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10.1080/01418619908210309

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Günthe, W., Schöllhorn, R., Epple, M., Siegle, H., Thomsen, C. H., Kabius, B., Poppe, U., Schubert, J., & Zander, W. (1999). Hydrogen and water intercalation into YBa₂Cu₃O₇-_δ: Structural properties of H₂YBa₂Cu₃O_8-δ. Philosophical Magazine A: Physics of Condensed Matter, Structure, Defects and Mechanical Properties, 79(2), 449-466. https://doi.org/10.1080/01418619908210309

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abstract = "Structural properties of hydrogen- and water-intercalated superconductors YBa2Cu3O7-δare discussed on the basis of new high-resolution electron microscopy, electron diffraction, X-ray diffraction, extended X-ray absorption fine structure (EXAFS) and Raman measurements. The multistep intercalation reaction proceeding at temperatures below 200°C leads to significant changes in the crystal structure via shear transformation resulting in a highly crystalline end phase. A new structure model was proposed for YBa2Cu3O8-δwhich includes Cu-O single chains as in YBa2Cu3O7-δThis result differs in principle from all models proposed before.",

author = "W. G{\"u}nthe and R. Sch{\"o}llhorn and M. Epple and H. Siegle and Thomsen, {Ch H.} and B. Kabius and U. Poppe and J. Schubert and W. Zander",

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Günthe, W, Schöllhorn, R, Epple, M, Siegle, H, Thomsen, CH, Kabius, B, Poppe, U, Schubert, J & Zander, W 1999, 'Hydrogen and water intercalation into YBa₂Cu₃O₇-_δ: Structural properties of H₂YBa₂Cu₃O_8-δ', Philosophical Magazine A: Physics of Condensed Matter, Structure, Defects and Mechanical Properties, vol. 79, no. 2, pp. 449-466. https://doi.org/10.1080/01418619908210309

TY - JOUR

T1 - Hydrogen and water intercalation into YBa2Cu3O7-δ

T2 - Structural properties of H2YBa2Cu3O8-δ

AU - Günthe, W.

AU - Schöllhorn, R.

AU - Epple, M.

AU - Siegle, H.

AU - Thomsen, Ch H.

AU - Kabius, B.

AU - Poppe, U.

AU - Schubert, J.

AU - Zander, W.

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AB - Structural properties of hydrogen- and water-intercalated superconductors YBa2Cu3O7-δare discussed on the basis of new high-resolution electron microscopy, electron diffraction, X-ray diffraction, extended X-ray absorption fine structure (EXAFS) and Raman measurements. The multistep intercalation reaction proceeding at temperatures below 200°C leads to significant changes in the crystal structure via shear transformation resulting in a highly crystalline end phase. A new structure model was proposed for YBa2Cu3O8-δwhich includes Cu-O single chains as in YBa2Cu3O7-δThis result differs in principle from all models proposed before.

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Hydrogen and water intercalation into YBa₂Cu₃O₇-_δ: Structural properties of H₂YBa₂Cu₃O_8-δ

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