Abstract
The results of vibrational echo correlation spectroscopy with full phase information were used to examine aspects of the hydrogen bond dynamics of methanol-OD in CCl4. By using extremely short pulses, it was possible to excite the entire very broad hydroxyl-stretching band including the 1-2 transition. Vibrational echo correlation spectroscopy combined with detailed calculations made it possible to explicate the population dynamics of hydrogen bond evolution with considerable clarity and detail.
Original language | English (US) |
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Pages (from-to) | 12981-12997 |
Number of pages | 17 |
Journal | Journal of Chemical Physics |
Volume | 119 |
Issue number | 24 |
DOIs | |
State | Published - Dec 22 2003 |
All Science Journal Classification (ASJC) codes
- General Physics and Astronomy
- Physical and Theoretical Chemistry