Hydrogen bond dynamics probed with ultrafast infrared heterodyne-detected multidimensional vibrational stimulated echoes

John B. Asbury; Tobias Steinel; C. Stromberg; K. J. Gaffney; I. R. Piletic; Alexi Goun; M. D. Fayer

doi:10.1103/PhysRevLett.91.237402

Hydrogen bond dynamics probed with ultrafast infrared heterodyne-detected multidimensional vibrational stimulated echoes

John B. Asbury, Tobias Steinel, C. Stromberg, K. J. Gaffney, I. R. Piletic, Alexi Goun, M. D. Fayer

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120 Scopus citations

Abstract

Hydrogen bond dynamics are explicated with exceptional detail using multidimensional infrared vibrational echo correlation spectroscopy with full phase information. Probing the hydroxyl stretch of methanol-OD oligomers in [Formula presented], the dynamics of the evolving hydrogen bonded network are measured with ultrashort ([Formula presented]) pulses. The data along with detailed model calculations demonstrate that vibrational relaxation leads to selective hydrogen bond breaking on the red side of the spectrum (strongest hydrogen bonds) and the production of singly hydrogen bonded photoproducts.

Original language	English (US)
Journal	Physical review letters
Volume	91
Issue number	23
DOIs	https://doi.org/10.1103/PhysRevLett.91.237402
State	Published - 2003

All Science Journal Classification (ASJC) codes

General Physics and Astronomy

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10.1103/PhysRevLett.91.237402

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title = "Hydrogen bond dynamics probed with ultrafast infrared heterodyne-detected multidimensional vibrational stimulated echoes",

abstract = "Hydrogen bond dynamics are explicated with exceptional detail using multidimensional infrared vibrational echo correlation spectroscopy with full phase information. Probing the hydroxyl stretch of methanol-OD oligomers in [Formula presented], the dynamics of the evolving hydrogen bonded network are measured with ultrashort ([Formula presented]) pulses. The data along with detailed model calculations demonstrate that vibrational relaxation leads to selective hydrogen bond breaking on the red side of the spectrum (strongest hydrogen bonds) and the production of singly hydrogen bonded photoproducts.",

author = "Asbury, {John B.} and Tobias Steinel and C. Stromberg and Gaffney, {K. J.} and Piletic, {I. R.} and Alexi Goun and Fayer, {M. D.}",

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doi = "10.1103/PhysRevLett.91.237402",

language = "English (US)",

volume = "91",

journal = "Physical review letters",

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AU - Asbury, John B.

AU - Steinel, Tobias

AU - Stromberg, C.

AU - Gaffney, K. J.

AU - Piletic, I. R.

AU - Goun, Alexi

AU - Fayer, M. D.

PY - 2003

Y1 - 2003

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AB - Hydrogen bond dynamics are explicated with exceptional detail using multidimensional infrared vibrational echo correlation spectroscopy with full phase information. Probing the hydroxyl stretch of methanol-OD oligomers in [Formula presented], the dynamics of the evolving hydrogen bonded network are measured with ultrashort ([Formula presented]) pulses. The data along with detailed model calculations demonstrate that vibrational relaxation leads to selective hydrogen bond breaking on the red side of the spectrum (strongest hydrogen bonds) and the production of singly hydrogen bonded photoproducts.

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VL - 91

JO - Physical review letters

JF - Physical review letters

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ER -

Hydrogen bond dynamics probed with ultrafast infrared heterodyne-detected multidimensional vibrational stimulated echoes

Abstract

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