TY - GEN
T1 - Hydrogen storage via hydrogen spillover to nanoporous materials
AU - Lueking, Angela D.
AU - Li, Qixiu
PY - 2009
Y1 - 2009
N2 - Hydrogen storage in nanoporous materials can be increased by hydrogen spillover from a supported catalyst to the high-surface area support. The process increases the active temperature of adsorption to the nanoporous support, typically to moderate temperatures (i.e. 300K). The overall surface coverage of hydrogen can be optimized by enhancing the rate of spillover from the catalyst to the nanoporous support and/or increasing the binding energy of atomic hydrogen to specialized surface binding sites. The pressure dependence of hydrogen spillover, the effect of surface chemistry, porosity, metal-support interface, and catalyst loading will be discussed. New results using carbide-derived-carbons, tailored activated carbons, and metal-organic frameworks will be discussed.
AB - Hydrogen storage in nanoporous materials can be increased by hydrogen spillover from a supported catalyst to the high-surface area support. The process increases the active temperature of adsorption to the nanoporous support, typically to moderate temperatures (i.e. 300K). The overall surface coverage of hydrogen can be optimized by enhancing the rate of spillover from the catalyst to the nanoporous support and/or increasing the binding energy of atomic hydrogen to specialized surface binding sites. The pressure dependence of hydrogen spillover, the effect of surface chemistry, porosity, metal-support interface, and catalyst loading will be discussed. New results using carbide-derived-carbons, tailored activated carbons, and metal-organic frameworks will be discussed.
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M3 - Conference contribution
AN - SCOPUS:78649518393
SN - 9780841224414
T3 - ACS National Meeting Book of Abstracts
BT - American Chemical Society - 237th National Meeting and Exposition, ACS 2009, Abstracts of Scientific Papers
T2 - 237th National Meeting and Exposition of the American Chemical Society, ACS 2009
Y2 - 22 March 2009 through 26 March 2009
ER -