Hydrogen/nitrogen dioxide kinetics: Derived rate data for the reaction H2 + NO2 = HONO + H at 833 K

Mark A. Mueller; Jeffrey L. Gatto; Richard A. Yetter; Frederick L. Dryer

doi:10.1016/S0010-2180(99)00118-2

Hydrogen/nitrogen dioxide kinetics: Derived rate data for the reaction H₂ + NO₂ = HONO + H at 833 K

Mark A. Mueller, Jeffrey L. Gatto, Richard A. Yetter, Frederick L. Dryer

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

New experimental data were obtained for the reaction of H2 with NO2 at temperatures near 833 K and pressures between 1.2 and 5.0 atm. Numerical predictions from previously published reaction mechanism showed good agreement with measured species profiles at 833 K only when the recommended rate constant for H2 + NO2 = HONO + H is reduced by a factor of 30. Steady-state analyses of a simple five-step mechanism were used to develop an analytical expression for N2 consumption that well predicts the high-pressure data.

Original language	English (US)
Pages (from-to)	589-594
Number of pages	6
Journal	Combustion and Flame
Volume	120
Issue number	4
DOIs	https://doi.org/10.1016/S0010-2180(99)00118-2
State	Published - Mar 2000

All Science Journal Classification (ASJC) codes

General Chemistry
General Chemical Engineering
Fuel Technology
Energy Engineering and Power Technology
General Physics and Astronomy

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10.1016/S0010-2180(99)00118-2

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@article{d1420f2c6a934d77b20e8b62852649c6,

title = "Hydrogen/nitrogen dioxide kinetics: Derived rate data for the reaction H2 + NO2 = HONO + H at 833 K",

abstract = "New experimental data were obtained for the reaction of H2 with NO2 at temperatures near 833 K and pressures between 1.2 and 5.0 atm. Numerical predictions from previously published reaction mechanism showed good agreement with measured species profiles at 833 K only when the recommended rate constant for H2 + NO2 = HONO + H is reduced by a factor of 30. Steady-state analyses of a simple five-step mechanism were used to develop an analytical expression for N2 consumption that well predicts the high-pressure data.",

author = "Mueller, {Mark A.} and Gatto, {Jeffrey L.} and Yetter, {Richard A.} and Dryer, {Frederick L.}",

note = "Funding Information: The work reported in the Masters thesis of J.L.G. was supported by the Office of Naval Research under Contract No. N00014-90-J-4092 with Dr. R. S. Miller as Technical Monitor. Additional research and analyses reported here were supported by the U.S. Department of Energy, Chemical Sciences Division, Office of Basic Energy Sciences under Contract No. DE-FG02-86ER-13503 with Dr. William Kirchhoff as Technical Monitor. MAM wishes to acknowledge honorary fellowship support from Princeton University. The authors also thank Mr. Paul Michniewicz for his assistance in performing the experiments.",

year = "2000",

month = mar,

doi = "10.1016/S0010-2180(99)00118-2",

language = "English (US)",

volume = "120",

pages = "589--594",

journal = "Combustion and Flame",

issn = "0010-2180",

publisher = "Elsevier Inc.",

number = "4",

}

TY - JOUR

T1 - Hydrogen/nitrogen dioxide kinetics

T2 - Derived rate data for the reaction H2 + NO2 = HONO + H at 833 K

AU - Mueller, Mark A.

AU - Gatto, Jeffrey L.

AU - Yetter, Richard A.

AU - Dryer, Frederick L.

N1 - Funding Information: The work reported in the Masters thesis of J.L.G. was supported by the Office of Naval Research under Contract No. N00014-90-J-4092 with Dr. R. S. Miller as Technical Monitor. Additional research and analyses reported here were supported by the U.S. Department of Energy, Chemical Sciences Division, Office of Basic Energy Sciences under Contract No. DE-FG02-86ER-13503 with Dr. William Kirchhoff as Technical Monitor. MAM wishes to acknowledge honorary fellowship support from Princeton University. The authors also thank Mr. Paul Michniewicz for his assistance in performing the experiments.

PY - 2000/3

Y1 - 2000/3

N2 - New experimental data were obtained for the reaction of H2 with NO2 at temperatures near 833 K and pressures between 1.2 and 5.0 atm. Numerical predictions from previously published reaction mechanism showed good agreement with measured species profiles at 833 K only when the recommended rate constant for H2 + NO2 = HONO + H is reduced by a factor of 30. Steady-state analyses of a simple five-step mechanism were used to develop an analytical expression for N2 consumption that well predicts the high-pressure data.

AB - New experimental data were obtained for the reaction of H2 with NO2 at temperatures near 833 K and pressures between 1.2 and 5.0 atm. Numerical predictions from previously published reaction mechanism showed good agreement with measured species profiles at 833 K only when the recommended rate constant for H2 + NO2 = HONO + H is reduced by a factor of 30. Steady-state analyses of a simple five-step mechanism were used to develop an analytical expression for N2 consumption that well predicts the high-pressure data.

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U2 - 10.1016/S0010-2180(99)00118-2

DO - 10.1016/S0010-2180(99)00118-2

M3 - Article

AN - SCOPUS:0034160133

SN - 0010-2180

VL - 120

SP - 589

EP - 594

JO - Combustion and Flame

JF - Combustion and Flame

IS - 4

ER -

Hydrogen/nitrogen dioxide kinetics: Derived rate data for the reaction H₂ + NO₂ = HONO + H at 833 K

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