Hydrophilic polyphosphazenes as hydrogels: radiation cross-linking and hydrogel characteristics of poly [bis (methoxyethoxyethoxy)phosphazene]

H. E. Allcock; S. Kwon; G. H. Riding; R. J. Fitzpatrick; J. L. Bennett

doi:10.1016/0142-9612(88)90046-4

Hydrophilic polyphosphazenes as hydrogels: radiation cross-linking and hydrogel characteristics of poly [bis (methoxyethoxyethoxy)phosphazene]

H. E. Allcock
, S. Kwon
, G. H. Riding
, R. J. Fitzpatrick
, J. L. Bennett

Research output: Contribution to journal › Article › peer-review

91 Scopus citations

Abstract

The water-soluble polyphosphazene, [NP(OCH₂CH₂OCH₂CH₂OCH₃)₂]_n, cross-links when exposed to γ rays to form hydrophilic, water-swellable membranes and hydrogels. The degree of cross-linking increases with irradiation dose in a manner that can be utilized to change the properties, γ irradiation studies of the small molecule model compound, [NP(OCH₂CH₂OCH₂CH₂OCH₃)₂]₄, were also carried out to probe the relationship between irradiation dose and cross-link density.

Original language	English (US)
Pages (from-to)	509-513
Number of pages	5
Journal	Biomaterials
Volume	9
Issue number	6
DOIs	https://doi.org/10.1016/0142-9612(88)90046-4
State	Published - Nov 1988

All Science Journal Classification (ASJC) codes

Biophysics
Bioengineering
Ceramics and Composites
Biomaterials
Mechanics of Materials

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10.1016/0142-9612(88)90046-4

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@article{f21dab569c3f48589fdab11450810abf,

title = "Hydrophilic polyphosphazenes as hydrogels: radiation cross-linking and hydrogel characteristics of poly [bis (methoxyethoxyethoxy)phosphazene]",

abstract = "The water-soluble polyphosphazene, [NP(OCH2CH2OCH2CH2OCH3)2]n, cross-links when exposed to γ rays to form hydrophilic, water-swellable membranes and hydrogels. The degree of cross-linking increases with irradiation dose in a manner that can be utilized to change the properties, γ irradiation studies of the small molecule model compound, [NP(OCH2CH2OCH2CH2OCH3)2]4, were also carried out to probe the relationship between irradiation dose and cross-link density.",

author = "Allcock, \{H. E.\} and S. Kwon and Riding, \{G. H.\} and Fitzpatrick, \{R. J.\} and Bennett, \{J. L.\}",

note = "Funding Information: This work was supported by the Public Health Service through grant number 5 ROl HLl 1418 from the National Heart, Lung and Blood Institute. The y irradiations were carried out by J.J. Bonner.",

year = "1988",

month = nov,

doi = "10.1016/0142-9612(88)90046-4",

language = "English (US)",

volume = "9",

pages = "509--513",

journal = "Biomaterials",

issn = "0142-9612",

publisher = "Elsevier Limited",

number = "6",

}

TY - JOUR

T1 - Hydrophilic polyphosphazenes as hydrogels

T2 - radiation cross-linking and hydrogel characteristics of poly [bis (methoxyethoxyethoxy)phosphazene]

AU - Allcock, H. E.

AU - Kwon, S.

AU - Riding, G. H.

AU - Fitzpatrick, R. J.

AU - Bennett, J. L.

N1 - Funding Information: This work was supported by the Public Health Service through grant number 5 ROl HLl 1418 from the National Heart, Lung and Blood Institute. The y irradiations were carried out by J.J. Bonner.

PY - 1988/11

Y1 - 1988/11

N2 - The water-soluble polyphosphazene, [NP(OCH2CH2OCH2CH2OCH3)2]n, cross-links when exposed to γ rays to form hydrophilic, water-swellable membranes and hydrogels. The degree of cross-linking increases with irradiation dose in a manner that can be utilized to change the properties, γ irradiation studies of the small molecule model compound, [NP(OCH2CH2OCH2CH2OCH3)2]4, were also carried out to probe the relationship between irradiation dose and cross-link density.

AB - The water-soluble polyphosphazene, [NP(OCH2CH2OCH2CH2OCH3)2]n, cross-links when exposed to γ rays to form hydrophilic, water-swellable membranes and hydrogels. The degree of cross-linking increases with irradiation dose in a manner that can be utilized to change the properties, γ irradiation studies of the small molecule model compound, [NP(OCH2CH2OCH2CH2OCH3)2]4, were also carried out to probe the relationship between irradiation dose and cross-link density.

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U2 - 10.1016/0142-9612(88)90046-4

DO - 10.1016/0142-9612(88)90046-4

M3 - Article

C2 - 3224138

AN - SCOPUS:0024119433

SN - 0142-9612

VL - 9

SP - 509

EP - 513

JO - Biomaterials

JF - Biomaterials

IS - 6

ER -

Hydrophilic polyphosphazenes as hydrogels: radiation cross-linking and hydrogel characteristics of poly [bis (methoxyethoxyethoxy)phosphazene]

Abstract

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