Impact of cleaning procedures on restoring cathode performance for microbial fuel cells treating domestic wastewater

Ruggero Rossi; Xu Wang; Wulin Yang; Bruce E. Logan

doi:10.1016/j.biortech.2019.121759

Impact of cleaning procedures on restoring cathode performance for microbial fuel cells treating domestic wastewater

Ruggero Rossi, Xu Wang, Wulin Yang, Bruce E. Logan

Research output: Contribution to journal › Article › peer-review

31 Scopus citations

Abstract

Degradation of cathode performance over time is one of the major drawbacks in applications of microbial fuel cells (MFCs) for wastewater treatment. Over a two month period the resistance of air cathodes (R_Ct) with a polyvinylidene fluoride (PVDF) diffusion layer increased of 111% from 70 ± 10 mΩ m² to 148 ± 32 mΩ m². Soaking the cathodes in hydrochloric acid (100 mM HCl) restored cathode performance to R_Ct = 74 ± 17 mΩ m². Steam, ethanol, or sodium hydroxide treatment produced only a small change in performance, and slightly increased R_Ct. With a polytetrafluoroethylene (PTFE) diffusion layer on the cathodes, R_Ct increased from 54 ± 14 mΩ m² to 342 ± 142 mΩ m² after two months of operation. The acid concentration was critical for effectiveness in cleaning, as HCl (100 mM) decreased R_Ct to 28 ± 8 mΩ m². A lower concentration of HCl (<1 mM) showed no improvement, and vinegar (5% acetic acid) produced 48 ± 4 mΩ m².

Original language	English (US)
Article number	121759
Journal	Bioresource technology
Volume	290
DOIs	https://doi.org/10.1016/j.biortech.2019.121759
State	Published - Oct 2019

All Science Journal Classification (ASJC) codes

Bioengineering
Environmental Engineering
Renewable Energy, Sustainability and the Environment
Waste Management and Disposal

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/j.biortech.2019.121759

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title = "Impact of cleaning procedures on restoring cathode performance for microbial fuel cells treating domestic wastewater",

abstract = "Degradation of cathode performance over time is one of the major drawbacks in applications of microbial fuel cells (MFCs) for wastewater treatment. Over a two month period the resistance of air cathodes (RCt) with a polyvinylidene fluoride (PVDF) diffusion layer increased of 111% from 70 ± 10 mΩ m2 to 148 ± 32 mΩ m2. Soaking the cathodes in hydrochloric acid (100 mM HCl) restored cathode performance to RCt = 74 ± 17 mΩ m2. Steam, ethanol, or sodium hydroxide treatment produced only a small change in performance, and slightly increased RCt. With a polytetrafluoroethylene (PTFE) diffusion layer on the cathodes, RCt increased from 54 ± 14 mΩ m2 to 342 ± 142 mΩ m2 after two months of operation. The acid concentration was critical for effectiveness in cleaning, as HCl (100 mM) decreased RCt to 28 ± 8 mΩ m2. A lower concentration of HCl (<1 mM) showed no improvement, and vinegar (5% acetic acid) produced 48 ± 4 mΩ m2.",

author = "Ruggero Rossi and Xu Wang and Wulin Yang and Logan, {Bruce E.}",

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doi = "10.1016/j.biortech.2019.121759",

language = "English (US)",

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AU - Rossi, Ruggero

AU - Wang, Xu

AU - Yang, Wulin

AU - Logan, Bruce E.

PY - 2019/10

Y1 - 2019/10

N2 - Degradation of cathode performance over time is one of the major drawbacks in applications of microbial fuel cells (MFCs) for wastewater treatment. Over a two month period the resistance of air cathodes (RCt) with a polyvinylidene fluoride (PVDF) diffusion layer increased of 111% from 70 ± 10 mΩ m2 to 148 ± 32 mΩ m2. Soaking the cathodes in hydrochloric acid (100 mM HCl) restored cathode performance to RCt = 74 ± 17 mΩ m2. Steam, ethanol, or sodium hydroxide treatment produced only a small change in performance, and slightly increased RCt. With a polytetrafluoroethylene (PTFE) diffusion layer on the cathodes, RCt increased from 54 ± 14 mΩ m2 to 342 ± 142 mΩ m2 after two months of operation. The acid concentration was critical for effectiveness in cleaning, as HCl (100 mM) decreased RCt to 28 ± 8 mΩ m2. A lower concentration of HCl (<1 mM) showed no improvement, and vinegar (5% acetic acid) produced 48 ± 4 mΩ m2.

AB - Degradation of cathode performance over time is one of the major drawbacks in applications of microbial fuel cells (MFCs) for wastewater treatment. Over a two month period the resistance of air cathodes (RCt) with a polyvinylidene fluoride (PVDF) diffusion layer increased of 111% from 70 ± 10 mΩ m2 to 148 ± 32 mΩ m2. Soaking the cathodes in hydrochloric acid (100 mM HCl) restored cathode performance to RCt = 74 ± 17 mΩ m2. Steam, ethanol, or sodium hydroxide treatment produced only a small change in performance, and slightly increased RCt. With a polytetrafluoroethylene (PTFE) diffusion layer on the cathodes, RCt increased from 54 ± 14 mΩ m2 to 342 ± 142 mΩ m2 after two months of operation. The acid concentration was critical for effectiveness in cleaning, as HCl (100 mM) decreased RCt to 28 ± 8 mΩ m2. A lower concentration of HCl (<1 mM) showed no improvement, and vinegar (5% acetic acid) produced 48 ± 4 mΩ m2.

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Impact of cleaning procedures on restoring cathode performance for microbial fuel cells treating domestic wastewater

Abstract

All Science Journal Classification (ASJC) codes

UN SDGs

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