In situ measurements of corona poling induced SHG in amorphous polymers

Manfred Eich; Ayusman Sen; Herbert Looser; Do Y. Yoon; Gary C. Bjorklund; Robert Twieg; Jerome D. Swalen

doi:10.1117/12.948224

In situ measurements of corona poling induced SHG in amorphous polymers

Manfred Eich, Ayusman Sen, Herbert Looser, Do Y. Yoon, Gary C. Bjorklund, Robert Twieg, Jerome D. Swalen

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17 Scopus citations

Abstract

In this paper we report for the first time in-situ measurements of corona poling induced SHG. We investigated a specially synthesized new amorphous polymer (PPNA) that contains p-nitroaniline as sidegroups covalently fixed to a polyethylene-type backbone. In addition, we did measurements on an amorphous alternating copolymer poly(vinylidenecyanide/vinyl-acetate) (PVDCN/VAc), known for its piezoelectric properties. In order to understand the nonlinear properties and their stability, an extensive characterization of the materials is necessary. Therefore, calorimetry, thermogravimetry, X-ray, dielectric relaxation, waveguide and absorption spectroscopy studies were performed. Fig. 1 shows the chemical structure of the polymers investigated.

Original language	English (US)
Pages (from-to)	128-135
Number of pages	8
Journal	Proceedings of SPIE - The International Society for Optical Engineering
Volume	971
DOIs	https://doi.org/10.1117/12.948224
State	Published - Dec 21 1988

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Computer Science Applications
Applied Mathematics
Electrical and Electronic Engineering

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AU - Eich, Manfred

AU - Sen, Ayusman

AU - Looser, Herbert

AU - Yoon, Do Y.

AU - Bjorklund, Gary C.

AU - Twieg, Robert

AU - Swalen, Jerome D.

PY - 1988/12/21

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N2 - In this paper we report for the first time in-situ measurements of corona poling induced SHG. We investigated a specially synthesized new amorphous polymer (PPNA) that contains p-nitroaniline as sidegroups covalently fixed to a polyethylene-type backbone. In addition, we did measurements on an amorphous alternating copolymer poly(vinylidenecyanide/vinyl-acetate) (PVDCN/VAc), known for its piezoelectric properties. In order to understand the nonlinear properties and their stability, an extensive characterization of the materials is necessary. Therefore, calorimetry, thermogravimetry, X-ray, dielectric relaxation, waveguide and absorption spectroscopy studies were performed. Fig. 1 shows the chemical structure of the polymers investigated.

AB - In this paper we report for the first time in-situ measurements of corona poling induced SHG. We investigated a specially synthesized new amorphous polymer (PPNA) that contains p-nitroaniline as sidegroups covalently fixed to a polyethylene-type backbone. In addition, we did measurements on an amorphous alternating copolymer poly(vinylidenecyanide/vinyl-acetate) (PVDCN/VAc), known for its piezoelectric properties. In order to understand the nonlinear properties and their stability, an extensive characterization of the materials is necessary. Therefore, calorimetry, thermogravimetry, X-ray, dielectric relaxation, waveguide and absorption spectroscopy studies were performed. Fig. 1 shows the chemical structure of the polymers investigated.

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In situ measurements of corona poling induced SHG in amorphous polymers

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