In situ regeneration of the thermal stabilizer benzyl alcohol via ethanol in simulated jet fuels above 400°C

Leena Selvaraj; John B. Stallman; Chunshan Song; Michael M. Coleman

doi:10.1016/S0378-3820(96)01066-1

In situ regeneration of the thermal stabilizer benzyl alcohol via ethanol in simulated jet fuels above 400°C

Leena Selvaraj, John B. Stallman, Chunshan Song, Michael M. Coleman

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

Ethanol/benzyl alcohol mixtures are effective thermal stabilizers for jet fuels above 400°C. Ethanol, which itself is only a marginal thermal stabilizer, primarily serves to regenerate benzyl alcohol in situ by reducing benzaldehyde, the reaction product formed by the reaction of benzyl alcohol with the hydrocarbon radicals produced at these temperatures. Accordingly, in the presence of ethanol, less benzyl alcohol is necessary to thermally stabilize hydrocarbon fuels under the same conditions of time and temperature.

Original language	English (US)
Pages (from-to)	153-162
Number of pages	10
Journal	Fuel processing technology
Volume	50
Issue number	2-3
DOIs	https://doi.org/10.1016/S0378-3820(96)01066-1
State	Published - Feb 1997

All Science Journal Classification (ASJC) codes

General Chemical Engineering
Fuel Technology
Energy Engineering and Power Technology

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10.1016/S0378-3820(96)01066-1

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title = "In situ regeneration of the thermal stabilizer benzyl alcohol via ethanol in simulated jet fuels above 400°C",

abstract = "Ethanol/benzyl alcohol mixtures are effective thermal stabilizers for jet fuels above 400°C. Ethanol, which itself is only a marginal thermal stabilizer, primarily serves to regenerate benzyl alcohol in situ by reducing benzaldehyde, the reaction product formed by the reaction of benzyl alcohol with the hydrocarbon radicals produced at these temperatures. Accordingly, in the presence of ethanol, less benzyl alcohol is necessary to thermally stabilize hydrocarbon fuels under the same conditions of time and temperature.",

author = "Leena Selvaraj and Stallman, {John B.} and Chunshan Song and Coleman, {Michael M.}",

note = "Funding Information: This project was jointly supported by the US Department of Finergq. Pittchurgh Energy Technology Center and the U.S. Air Force Wright Laboratory/&x) Propulsion and Power Directorate. Wright-Patterson AFB. Funding was provided by the US DOE under contract DE-FGZ93PC92 104. We wish to thank Professor H. H. Schohert of{\textquoteleft} PSU for his encouragement and many helpful discussions.",

year = "1997",

month = feb,

doi = "10.1016/S0378-3820(96)01066-1",

language = "English (US)",

volume = "50",

pages = "153--162",

journal = "Fuel processing technology",

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publisher = "Elsevier B.V.",

number = "2-3",

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TY - JOUR

T1 - In situ regeneration of the thermal stabilizer benzyl alcohol via ethanol in simulated jet fuels above 400°C

AU - Selvaraj, Leena

AU - Stallman, John B.

AU - Song, Chunshan

AU - Coleman, Michael M.

N1 - Funding Information: This project was jointly supported by the US Department of Finergq. Pittchurgh Energy Technology Center and the U.S. Air Force Wright Laboratory/&x) Propulsion and Power Directorate. Wright-Patterson AFB. Funding was provided by the US DOE under contract DE-FGZ93PC92 104. We wish to thank Professor H. H. Schohert of‘ PSU for his encouragement and many helpful discussions.

PY - 1997/2

Y1 - 1997/2

N2 - Ethanol/benzyl alcohol mixtures are effective thermal stabilizers for jet fuels above 400°C. Ethanol, which itself is only a marginal thermal stabilizer, primarily serves to regenerate benzyl alcohol in situ by reducing benzaldehyde, the reaction product formed by the reaction of benzyl alcohol with the hydrocarbon radicals produced at these temperatures. Accordingly, in the presence of ethanol, less benzyl alcohol is necessary to thermally stabilize hydrocarbon fuels under the same conditions of time and temperature.

AB - Ethanol/benzyl alcohol mixtures are effective thermal stabilizers for jet fuels above 400°C. Ethanol, which itself is only a marginal thermal stabilizer, primarily serves to regenerate benzyl alcohol in situ by reducing benzaldehyde, the reaction product formed by the reaction of benzyl alcohol with the hydrocarbon radicals produced at these temperatures. Accordingly, in the presence of ethanol, less benzyl alcohol is necessary to thermally stabilize hydrocarbon fuels under the same conditions of time and temperature.

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ER -

In situ regeneration of the thermal stabilizer benzyl alcohol via ethanol in simulated jet fuels above 400°C

Abstract

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