In situ structure characterization of Pb(Yb 1/2Nb 1/2)O 3-PbTiO 3 crystals under high pressure-temperature

Lingping Kong; Luhong Wang; Shujun Zhang; Oliver Tschauner; Yusheng Zhao; Wenge Yang; Haozhe Liu; Ho Kwang Mao

doi:10.1063/1.4742165

In situ structure characterization of Pb(Yb _1/2Nb _1/2)O ₃-PbTiO ₃ crystals under high pressure-temperature

Lingping Kong
, Luhong Wang
, Shujun Zhang
, Oliver Tschauner
, Yusheng Zhao
, Wenge Yang
, Haozhe Liu
, Ho Kwang Mao

Materials Research Institute (MRI)

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

The stability field of the piezoelectric/ferroelectric phase of solid solution 0.47Pb(Yb _1/2Nb _1/2)O ₃-0.53PbTiO ₃ (PYN-PT) has been studied using in situ x-ray diffraction (XRD) and Raman spectroscopy techniques under high pressure and high temperature conditions to observe the evolution of features. PYN-PT remains in the piezoelectric tetragonal phase up to approximately 6.5 GPa at room temperature then transforms to a paraelectric cubic phase, which exhibits local disorder. The cubic phase is stable up to 50 GPa. Based on the high pressure and high temperature XRD results, we present a pressure-temperature phase diagram of PYN-PT which constraints the stability region of the ferroelectric phase.

Original language	English (US)
Article number	062904
Journal	Applied Physics Letters
Volume	101
Issue number	6
DOIs	https://doi.org/10.1063/1.4742165
State	Published - Aug 6 2012

All Science Journal Classification (ASJC) codes

Physics and Astronomy (miscellaneous)

Access to Document

10.1063/1.4742165

Cite this

@article{9eba476e2b5140daa83b7c5b0c65c81f,

title = "In situ structure characterization of Pb(Yb 1/2Nb 1/2)O 3-PbTiO 3 crystals under high pressure-temperature",

abstract = "The stability field of the piezoelectric/ferroelectric phase of solid solution 0.47Pb(Yb 1/2Nb 1/2)O 3-0.53PbTiO 3 (PYN-PT) has been studied using in situ x-ray diffraction (XRD) and Raman spectroscopy techniques under high pressure and high temperature conditions to observe the evolution of features. PYN-PT remains in the piezoelectric tetragonal phase up to approximately 6.5 GPa at room temperature then transforms to a paraelectric cubic phase, which exhibits local disorder. The cubic phase is stable up to 50 GPa. Based on the high pressure and high temperature XRD results, we present a pressure-temperature phase diagram of PYN-PT which constraints the stability region of the ferroelectric phase.",

author = "Lingping Kong and Luhong Wang and Shujun Zhang and Oliver Tschauner and Yusheng Zhao and Wenge Yang and Haozhe Liu and Mao, \{Ho Kwang\}",

note = "Funding Information: We thank the support from the National Natural Science Foundation of China (No. 10975042), Heilongjiang Province Outstanding Youth Scientific Funds (JC201005) and NSF (E200948), and Basic Research Excellent Talents Program (HIT.BRET1.2010002) and Oversea Collaborative Base Project in Harbin Institute of Technology. HPSynC is supported as part of EFree, an Energy Frontier Research Center funded by the U.S. Department of Energy (DOE), Office of Science, Office of Basic Energy Sciences (BES) under Award Number DE-SC0001057. HPCAT was supported by DOE-BES, DOE-NNSA (CDAC), NSF. APS is supported by DOE-BES under Contract No. DE-AC02-06CH11357. L.K. thanks support of the Chinese Scholarship Council. We are grateful to Dr. Changyong Park and Dr. Stanislav Sinogeikin at HPCAT, APS for help with these experiments.",

year = "2012",

month = aug,

day = "6",

doi = "10.1063/1.4742165",

language = "English (US)",

volume = "101",

journal = "Applied Physics Letters",

issn = "0003-6951",

publisher = "American Institute of Physics",

number = "6",

}

TY - JOUR

T1 - In situ structure characterization of Pb(Yb 1/2Nb 1/2)O 3-PbTiO 3 crystals under high pressure-temperature

AU - Kong, Lingping

AU - Wang, Luhong

AU - Zhang, Shujun

AU - Tschauner, Oliver

AU - Zhao, Yusheng

AU - Yang, Wenge

AU - Liu, Haozhe

AU - Mao, Ho Kwang

N1 - Funding Information: We thank the support from the National Natural Science Foundation of China (No. 10975042), Heilongjiang Province Outstanding Youth Scientific Funds (JC201005) and NSF (E200948), and Basic Research Excellent Talents Program (HIT.BRET1.2010002) and Oversea Collaborative Base Project in Harbin Institute of Technology. HPSynC is supported as part of EFree, an Energy Frontier Research Center funded by the U.S. Department of Energy (DOE), Office of Science, Office of Basic Energy Sciences (BES) under Award Number DE-SC0001057. HPCAT was supported by DOE-BES, DOE-NNSA (CDAC), NSF. APS is supported by DOE-BES under Contract No. DE-AC02-06CH11357. L.K. thanks support of the Chinese Scholarship Council. We are grateful to Dr. Changyong Park and Dr. Stanislav Sinogeikin at HPCAT, APS for help with these experiments.

PY - 2012/8/6

Y1 - 2012/8/6

N2 - The stability field of the piezoelectric/ferroelectric phase of solid solution 0.47Pb(Yb 1/2Nb 1/2)O 3-0.53PbTiO 3 (PYN-PT) has been studied using in situ x-ray diffraction (XRD) and Raman spectroscopy techniques under high pressure and high temperature conditions to observe the evolution of features. PYN-PT remains in the piezoelectric tetragonal phase up to approximately 6.5 GPa at room temperature then transforms to a paraelectric cubic phase, which exhibits local disorder. The cubic phase is stable up to 50 GPa. Based on the high pressure and high temperature XRD results, we present a pressure-temperature phase diagram of PYN-PT which constraints the stability region of the ferroelectric phase.

AB - The stability field of the piezoelectric/ferroelectric phase of solid solution 0.47Pb(Yb 1/2Nb 1/2)O 3-0.53PbTiO 3 (PYN-PT) has been studied using in situ x-ray diffraction (XRD) and Raman spectroscopy techniques under high pressure and high temperature conditions to observe the evolution of features. PYN-PT remains in the piezoelectric tetragonal phase up to approximately 6.5 GPa at room temperature then transforms to a paraelectric cubic phase, which exhibits local disorder. The cubic phase is stable up to 50 GPa. Based on the high pressure and high temperature XRD results, we present a pressure-temperature phase diagram of PYN-PT which constraints the stability region of the ferroelectric phase.

UR - https://www.scopus.com/pages/publications/84865125118

UR - https://www.scopus.com/pages/publications/84865125118#tab=citedBy

U2 - 10.1063/1.4742165

DO - 10.1063/1.4742165

M3 - Article

AN - SCOPUS:84865125118

SN - 0003-6951

VL - 101

JO - Applied Physics Letters

JF - Applied Physics Letters

IS - 6

M1 - 062904

ER -

In situ structure characterization of Pb(Yb _1/2Nb _1/2)O ₃-PbTiO ₃ crystals under high pressure-temperature

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this