Influence of Aliphatic versus Aromatic Ligand Passivation on Intersystem Crossing in Au₂₅(SR)₁₈^-

Keyphrases

• Aromatic Ligand 100%
• Ligand Passivation 100%
• Intersystem Crossing 100%
• Monolayer-protected Clusters 100%
• Au25 100%
• Electronic Relaxation 28%
• Ligand-dependent 28%
• Acoustic Mode 28%
• Ligand Structure 28%
• Protecting Ligand 28%
• Structural Change 14%
• Vibrational Modes 14%
• Aromatics 14%
• Ligand-independent 14%
• Steric Effect 14%
• Relaxation Dynamics 14%
• Quadrupolar 14%
• Femtosecond 14%
• Picosecond 14%
• Thiolate 14%
• Relaxation Rate 14%
• Femtosecond Transient Absorption Spectroscopy 14%
• Metal Core 14%
• Competing Ligands 14%
• Internal Conversion 14%
• Non-radiative Decay 14%
• Carrier Relaxation 14%
• Relaxation Pathways 14%
• Gold Monolayer 14%
• Semiring 14%
• Hydrocarbon Structure 14%

Chemistry

• Chemical Passivation 100%
• Intersystem Crossing [Singlet->triplet] 100%
• Monolayers 100%
• Relaxation 71%
• electronics 28%
• Ligand Structure 28%
• Metallocene 14%
• Steric Effect 14%
• Absorption Spectroscopy 14%
• Internal Conversion 14%