TY - JOUR
T1 - Insertion of imines into palladium - acyl bonds
T2 - Towards metal-catalyzed alternating copolymerization of imines with carbon monoxide to form polypeptides
AU - Kacker, Smita
AU - Kim, Jang Sub
AU - Sen, Ayusman
PY - 1998/5/18
Y1 - 1998/5/18
N2 - From a methyl ligand, CO, and an imine a chelating amide ligand is formed by insertion of the C=N bond into the metal-acyl bond in cationic palladium(II) complexes (see reaction below). The cationic acylpalladium complexes are obtained from CO and readily accessible palladium starting materials. LL = diphosphane ligand.
AB - From a methyl ligand, CO, and an imine a chelating amide ligand is formed by insertion of the C=N bond into the metal-acyl bond in cationic palladium(II) complexes (see reaction below). The cationic acylpalladium complexes are obtained from CO and readily accessible palladium starting materials. LL = diphosphane ligand.
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U2 - 10.1002/(SICI)1521-3773(19980518)37:9<1251::AID-ANIE1251>3.0.CO;2-4
DO - 10.1002/(SICI)1521-3773(19980518)37:9<1251::AID-ANIE1251>3.0.CO;2-4
M3 - Article
AN - SCOPUS:0344765502
SN - 1433-7851
VL - 37
SP - 1251
EP - 1253
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 9
ER -