Insertion of imines into palladium - acyl bonds: Towards metal-catalyzed alternating copolymerization of imines with carbon monoxide to form polypeptides

Smita Kacker; Jang Sub Kim; Ayusman Sen

doi:10.1002/(SICI)1521-3773(19980518)37:9<1251::AID-ANIE1251>3.0.CO;2-4

Insertion of imines into palladium - acyl bonds: Towards metal-catalyzed alternating copolymerization of imines with carbon monoxide to form polypeptides

Smita Kacker
, Jang Sub Kim
, Ayusman Sen

Chemistry

Research output: Contribution to journal › Article › peer-review

73 Scopus citations

Abstract

From a methyl ligand, CO, and an imine a chelating amide ligand is formed by insertion of the C=N bond into the metal-acyl bond in cationic palladium(II) complexes (see reaction below). The cationic acylpalladium complexes are obtained from CO and readily accessible palladium starting materials. LL = diphosphane ligand.

Original language	English (US)
Pages (from-to)	1251-1253
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	37
Issue number	9
DOIs	https://doi.org/10.1002/(SICI)1521-3773(19980518)37:9<1251::AID-ANIE1251>3.0.CO;2-4
State	Published - May 18 1998

All Science Journal Classification (ASJC) codes

Catalysis
General Chemistry

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10.1002/(SICI)1521-3773(19980518)37:9<1251::AID-ANIE1251>3.0.CO;2-4

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title = "Insertion of imines into palladium - acyl bonds: Towards metal-catalyzed alternating copolymerization of imines with carbon monoxide to form polypeptides",

abstract = "From a methyl ligand, CO, and an imine a chelating amide ligand is formed by insertion of the C=N bond into the metal-acyl bond in cationic palladium(II) complexes (see reaction below). The cationic acylpalladium complexes are obtained from CO and readily accessible palladium starting materials. LL = diphosphane ligand.",

author = "Smita Kacker and Kim, \{Jang Sub\} and Ayusman Sen",

year = "1998",

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journal = "Angewandte Chemie - International Edition",

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T1 - Insertion of imines into palladium - acyl bonds

T2 - Towards metal-catalyzed alternating copolymerization of imines with carbon monoxide to form polypeptides

AU - Kacker, Smita

AU - Kim, Jang Sub

AU - Sen, Ayusman

PY - 1998/5/18

Y1 - 1998/5/18

N2 - From a methyl ligand, CO, and an imine a chelating amide ligand is formed by insertion of the C=N bond into the metal-acyl bond in cationic palladium(II) complexes (see reaction below). The cationic acylpalladium complexes are obtained from CO and readily accessible palladium starting materials. LL = diphosphane ligand.

AB - From a methyl ligand, CO, and an imine a chelating amide ligand is formed by insertion of the C=N bond into the metal-acyl bond in cationic palladium(II) complexes (see reaction below). The cationic acylpalladium complexes are obtained from CO and readily accessible palladium starting materials. LL = diphosphane ligand.

UR - https://www.scopus.com/pages/publications/0344765502

UR - https://www.scopus.com/pages/publications/0344765502#tab=citedBy

U2 - 10.1002/(SICI)1521-3773(19980518)37:9<1251::AID-ANIE1251>3.0.CO;2-4

DO - 10.1002/(SICI)1521-3773(19980518)37:9<1251::AID-ANIE1251>3.0.CO;2-4

M3 - Article

AN - SCOPUS:0344765502

SN - 1433-7851

VL - 37

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 9

ER -

Insertion of imines into palladium - acyl bonds: Towards metal-catalyzed alternating copolymerization of imines with carbon monoxide to form polypeptides

Abstract

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