Interdiffusion across solid electrolyte-electrode interface

Jia Mian Hu; Linyun Liang; Yanzhou Ji; Liang Hong; Kirk Gerdes; Long Qing Chen

doi:10.1063/1.4879835

Interdiffusion across solid electrolyte-electrode interface

Jia Mian Hu
, Linyun Liang
, Yanzhou Ji
, Liang Hong
, Kirk Gerdes
, Long Qing Chen

Materials Science and Engineering

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

A phase-field model is developed for studying the cation interdiffusion across electrolyte-electrode interfaces in solid oxide fuel cell (SOFC) that can be contributing to long timescale performance degradation. Demonstrated on an interface between an 8%molY₂O₃-stabilized ZrO₂ and a La_0.65Sr_0.3MnO_3-x typically used in SOFC, time-dependent evolution of the cation interdiffusion profiles are predicted by linking the phase-field model to a diffusion equation. The simulated interdiffusion profiles agree with independent experimental data in both time and space domains at different temperatures.

Original language	English (US)
Article number	213907
Journal	Applied Physics Letters
Volume	104
Issue number	21
DOIs	https://doi.org/10.1063/1.4879835
State	Published - May 26 2014

All Science Journal Classification (ASJC) codes

Physics and Astronomy (miscellaneous)

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10.1063/1.4879835

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title = "Interdiffusion across solid electrolyte-electrode interface",

abstract = "A phase-field model is developed for studying the cation interdiffusion across electrolyte-electrode interfaces in solid oxide fuel cell (SOFC) that can be contributing to long timescale performance degradation. Demonstrated on an interface between an 8\%molY2O3-stabilized ZrO2 and a La0.65Sr0.3MnO3-x typically used in SOFC, time-dependent evolution of the cation interdiffusion profiles are predicted by linking the phase-field model to a diffusion equation. The simulated interdiffusion profiles agree with independent experimental data in both time and space domains at different temperatures.",

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AU - Hu, Jia Mian

AU - Liang, Linyun

AU - Ji, Yanzhou

AU - Hong, Liang

AU - Gerdes, Kirk

AU - Chen, Long Qing

PY - 2014/5/26

Y1 - 2014/5/26

N2 - A phase-field model is developed for studying the cation interdiffusion across electrolyte-electrode interfaces in solid oxide fuel cell (SOFC) that can be contributing to long timescale performance degradation. Demonstrated on an interface between an 8%molY2O3-stabilized ZrO2 and a La0.65Sr0.3MnO3-x typically used in SOFC, time-dependent evolution of the cation interdiffusion profiles are predicted by linking the phase-field model to a diffusion equation. The simulated interdiffusion profiles agree with independent experimental data in both time and space domains at different temperatures.

AB - A phase-field model is developed for studying the cation interdiffusion across electrolyte-electrode interfaces in solid oxide fuel cell (SOFC) that can be contributing to long timescale performance degradation. Demonstrated on an interface between an 8%molY2O3-stabilized ZrO2 and a La0.65Sr0.3MnO3-x typically used in SOFC, time-dependent evolution of the cation interdiffusion profiles are predicted by linking the phase-field model to a diffusion equation. The simulated interdiffusion profiles agree with independent experimental data in both time and space domains at different temperatures.

UR - https://www.scopus.com/pages/publications/84901774503

UR - https://www.scopus.com/pages/publications/84901774503#tab=citedBy

U2 - 10.1063/1.4879835

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M3 - Article

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SN - 0003-6951

VL - 104

JO - Applied Physics Letters

JF - Applied Physics Letters

IS - 21

M1 - 213907

ER -

Interdiffusion across solid electrolyte-electrode interface

Abstract

All Science Journal Classification (ASJC) codes

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